In this study, synthetic sulfonated polymers were used in order to enhance the rheological properties of drilling fluids. The capability of these polymers in reducing the effects of environmentally friendly, but harmful, pollutants such as cement, calcium chloride, gypsum as well as pH changes were investigated. In the present work, two sulfonated synthetic polymers, namely Polythin and Polydri...

A series of lactic/glycolic acid polymers with various molar ratios of lactic to glycolic acid and various molecular weights were synthesized using the ring-opening polymerization method. The polymerization conditions for the lactic/glycolic acid polymer synthesis were as follows: 150 degrees C, 700 microm Hg, 3 h, 0.03 wt% of catalyst (stannous 2-ethyl-hexanoate) concentration. The molecular w...

Cyclodextrins are a group of novel excipients, extensively used in the present pharmaceutical industry. Sometimes they show significant interactions with other conventional additives used in the formulation of dosage forms. The effect of β-cyclodextrin on the rheological properties of aqueous solutions of some selected viscosity modifiers was studied in the present work. β-cyclodextrin showed t...

In many practical flow situations solutions of flexible polymers are found to exhibit a well-known non-Newtonian viscosity enhancement effect. This is likely to be due to extensional components in the flow field, which can cause flexible polymer molecules to stretch and orientate, causing an increase in the extensional viscosity. This viscosity enhancement is important in many industrial applic...

We report novel polymeric materials that may be used as viscosity index improvers (VII) for lubricant applications. Our efforts included probing the comb-burst hyper-branched aryl polyester architecture for beneficial viscosity and friction behavior when utilized as an additive in a group I oil. The monomer was designed as to undergo polymerization via polycondensation within the architectural ...

rheological characteristics of al2o3, cuo and tio2 nano particles were investigated in oil asthe base fluid at 1 and 2 wt.%. constitutive relations for non-newtonian fluid were discussedbased on the power-law model. measured viscosities of each nanofluid were used to evaluatethe power-law and consistency index. results indicated that the nanofluid viscosity decreasedby increasing the concentrat...

The stretching response of a single collapsed homopolymer is studied using Brownian dynamic simulations. The irreversibly dissipated work is found to be dominated by internal friction effects below the collapse temperature, and the internal viscosity grows exponentially with the effective cohesive strength between monomers. These results explain friction effects of globular DNA and are relevant...

We briefly review the recent advances in the rheology of entangled polymers and identify emerging research trends and outstanding challenges, especially with respect to branched polymers. Emphasis is placed on the role of well-characterized model systems, as well as the synergy of synthesis-characterization, rheometry and modeling/simulations. The theoretical framework for understanding the obs...

The problem treated here is to determinethe viscosity effect on stresses, temperature change and chemical potential in a circular plate. The mathematical formulation is applied to two theories of thermoelastic diffusion developed by Sherief et al. [27] with one relaxation time and Kumar and Kansal [9]with two relaxation times. Laplace and Hankel transform techniques are used to obtain the expre...