We demonstrate a new technique for selectively growing gold nanoparticles on a patterned three-dimensional (3D) polymer microstructure. The technique integrates 3D direct writing of heterogeneous microstructures with nanoparticle synthesis. A digital micromirror device is employed as a dynamic mask in the digital projection photopolymerization process to build the heterogeneous microstructure l...

Polymer-modified bitumen emulsions present a safer and more environmentally friendly binder for enhancing the properties of roads. Cationic bitumen emulsion binders containing polymer latex were investigated using confocal laser scanning microscopy. The latex was incorporated into the bitumen emulsion by using four different addition methods and all emulsions were processed with a conventional ...

In this study the polymer composite specimen has been prepared by using polymer Polyvinylpyrrolidone (PVP) a Potassium iodide (KI) and alumina nanoparticles. The polymer composite specimens were developed by using solution cast techniques. The main objective of the project is to study microstructure, XRD, ionic conductivity, ionic transference number, glass transition temperature using DSC, mic...

We have developed a dynamic self-consistent field theory, without any adjustable parameters, for unentangled polymer blends under shear. Our model accounts for the interaction between polymers, and enables one to compute the evolution of the local rheology, microstructure, and the conformations of the polymer chains under shear self-consistently. We use this model to study the interfacial dynam...

The physical properties of the polymer product determine to a large extent its processability and applications. A large number of properties are directly related to the molecular mass distribution (MMD) of the polymer product. Besides the MMD, the polymer microstructure also plays an important role and influences to a large extent the thermal stability of the polymer product. Most of the therma...

Porous carbon with a foam-like microstructure has been synthesized by direct carbonization of porous coordination polymer (PCP). In situ generation of foaming agents by chemical reactions of ligands in PCP during carbonization provides a simple way to create lightweight carbon with a foam-like microstructure. Among several substituents, the nitro group has been proved to be the key to obtain th...

application of supramolecular polymer blending in preparation of materialswith adjustable mechanical properties is addressed. it is anticipated that the microstructure and properties of polymer blends are drastically controlled by the inter-molecular interactions. on this basis, the effect of strongly dimerising ureidopyrimidinone end groups (upy) with the capability of quadruple hydrogen bondi...

We report a method for fabricating permeable polymer microstructure barriers in polydimethylsiloxane (PDMS) microfluidic devices and the use of the devices to capture and transport DNA and cells. The polymer microstructure in a desired location in a fluidic channel is formed in situ by the polymerization of acrylamide and polyethylene diacrylate cross-linker (PEG-DA) monomer in a solution which...

We introduce a continuum model for polymer melts filled with nanoparticles capable of describing in a unified and self-consistent way their microstructure, phase behavior, and rheology in both the linear and nonlinear regimes. It is based on the Hamiltonian formulation of transport phenomena for fluids with a complex microstructure with the final dynamic equations derived by means of a generali...