The design and preparation of new polyester dendrimer, poly(ethylene oxide) hybrid systems for drug delivery and related therapeutic applications, are described. These systems consist of two covalently attached polyester dendrons, where one dendron provides multiple functional handles for the attachment of therapeutically active moieties, while the other is used for attachment of solubilizing p...

Poly (ether-block-amide) /poly (ethylene glycol)/ carbon nanotubes mixed matrix membranes have been successfully fabricated using solvent evaporation method to determine the effect of ethylene oxide groups on the performance of produced membranes. The effects of CNTs (2-8 wt%) and PEG (up to 50 wt%)were investigated in both single and mixed gas test setup in different temperature and pressure. ...

This review presents some examples obtained by molecular techniques in the study of non-ionic reverse micelles of poly(ethylene oxide) type surfactants: tetraethylene glycol mono-ndodecyl ether (C12E4), Triton X-100, and triblok copolymers poly(ethylene oxide)-blockpoly(propylene oxide)-blockpoly(ethylene oxide) (L62 and L64 Pluronics). By using specific spectral parameters of spin, fluorescenc...

Biofunctional block copolymers are becoming increasingly attractive materials as active components in biosensors and other nanoscale electronic devices. We have described two different classes of block copolymers with biofuctional properties. Biofunctionality for block copolymers is achieved through functionalization with appropriate biospecific ligands. We have synthesized block copolymers of ...

Pluronic poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (PEO-PPO-PEO) block copolymers are grafted with poly(vinyl pyrrolidone) by free radical polymerization of vinyl pyrrolidone with simultaneous chain transfer to the Pluronic in dioxane. This modified polymer has both thermal responsiveness and remarkable capacity to interact with a wide variety of hydrophilic and hydrop...

Synthetic routes towards new conjugates of hydrophilic zinc(II) phthalocyanine (ZnPc) with poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) (Pluronic P123) and poly(L-lactide) (PLLA), are described. The main semiproduct ZnPc was obtained by heating 4-nitrophthalimide with urea and zinc chloride, followed by the reduction step. Steglich esterification was used to synthesize tw...

The addition of multifunctional additives comprised of singleor double-ring aromatic cores decorated at their periphery with multiple hydrogen-bond-donating groups such as carboxylic acid and phenol is shown to induce microphase segregation of otherwise disordered Pluronic BCP (poly(ethylene oxide-propylene oxide-ethylene oxide)) surfactant melts, resulting in the formation of well-ordered supr...

The synthesis and properties of hybrid poly(ε-caprolactone) (PCL)–poly(ethylene oxide) (PEO) covalent adaptable networks have been investigated.