We developed a new semi-analytical source zone depletion model (SZDM) for multicomponent light nonaqueous phase liquids (LNAPLs) and incorporated this into an existing screening model for estimating cleanup times for chemical spills from railroad tank cars that previously considered only single-component LNAPLs. Results from the SZDM compare favorably to those from a three-dimensional numerical...

We propose a method that allows probing quantitatively the individual saturations of crudeoil/brine/mud-filtrate mixtures during imbibition-drainage experiments on a petroleum rock-system. The experiments have been also performed at different temperature and pressure conditions.

Heavy organics deposition is a common problem in oil industry, especially in oil production, transportation and processing. Wax or solid paraffin series are examples of heavy organics that deposit. Precipitation and crystallization of wax causes major difficulties in different processes. Based on multi-solid theory, a basic model is modified in this paper for wax precipitation in different oils...

Xylenes (mixtures of ortho-, meta-, and para-isomers) are used as industrial solvents, synthetic intermediates, and solvents in commercial products such as paints, coatings, adhesive removers, and paint thinners; they are also a component of gasoline. Xylenes are released to the atmosphere primarily as fugitive emissions from industrial sources (e.g., petroleum refineries, chemical plants), in ...

Fast pyrolysis oils are one source of renewable liquid fuels, which could be used as green fuels in a sustainable manner. The ASTM D664 method used to determine the acidic constituents in petroleum products, lubricants, and biodiesel requires mixtures of isopropyl alcohol (IPA) and toluene as solvent. The ASTM method also uses large quantities of solvents for the total acid number (TAN) determi...

A rapid, reliable method for the routine detection and quantification of biomarkers in petroleum was developed using the Agilent 7890A/7000A Series Triple Quadrupole GC/MS with backflushing using a Pressure Controlled Tee configuration. In a single run, diverse biomarkers from several transitions can be detected, confirmed, and quantified at levels as low as 2 ppm, with RSDs well below 5%. This...

The crystal and molecular structures of five succinimidyl halobenzoates are reported. Corresponding derivatives with the respective halo-radionuclide (18F, 76Br, 123I/124I/125I/131I) were prepared and used for the radiolabeling of biologically active (macro-)molecules (peptides, proteins, antibodies) under mild labeling conditions. All compounds were crystalized from petroleum ether/ethyl aceta...

The separations of alcohols with hydrophilic and hydrophobic parts, and the separation of aromatic mixtures, are extremely important processes in gas and petroleum industries. Choosing an adsorbent for performing this separation is the most important part of the process. Silica gel is used as an adsorbent is various techniques such as pressure swing adsorption (PSA) and gas and liquid chromatog...