Asphaltene precipitation occurs in petroleum fluids under certain unfavorable conditions, but can be controlled by tuning composition. Aromatic solvents in large quantities can prevent precipitation entirely and can dissolve already precipitated asphaltenes. Some polymeric surfactants can dissolve asphaltenes when added at much lower concentrations than required by aromatic solvents. Other disp...

The molecular properties of asphaltenes have been the subject of uncertainty in the literature; in particular the molecular architecture is still a matter of debate. Some literature reports provide evidence that the contrast of petroleum asphaltenes versus coal-derived asphaltenes is useful for understanding the governing principles of asphaltene identity. Here, we employ fluorescence correlati...

Operational discharges of hydrocarbons from maritime activities can have major cumulative impacts on marine ecosystems. Small quantities of oil (i.e., 10 ml) results in often lethally reduced thermoregulation in seabirds. Thin sheens of oil and drilling fluids form around offshore petroleum production structures from currently permissible operational discharges of hydrocarbons. Methodology was ...

A number of procedures to identify and measure the precipitates that result from petroleum fluids are presented. The Ž . fractions considered in this study include those in the categories of asphaltenes, resins, saturates paraffinrwax , aromatics, inorganic minerals and diamondoids. A combination of deposition techniques, separation by centrifuge, filtration, gas Ž . chromatography, gel-permeat...

Detection of the chemical constituents of hydrocarbons in the hydrocarbon-bearing fluid inclusions in diagenetic mineral cements, secondary fractures and overgrowths could be a useful indicator of the nature of oil in a basin. Microscopebased Raman spectroscopy is a non-destructive, optical vibrational spectroscopic technique that can precisely isolate and analyse hydrocarbon fluid inclusions (...

the conventional phase behavior study of petroleum reservoir fluids are valid when the reservoir temperature is far enough from the critical condition in which the material balance equation can be applied correctly. when the temperature of the reservoir is in the vicinity of the critical temperature the classical methods can’t determine the phase behavior of the mixture due to rapid phase chang...

Bioslurping is a new dynamic technology designed to efficiently recover free-floating petroleum hydrocarbons (free product) from the subsurface while simultaneously enhancing natural biodegradation of petroleum hydrocarbons in the vadose zone. Bioslurping is a vacuum-enhanced fluids pumping technology that simultaneously extracts groundwater, free product, and soil gas in the same process strea...

A procedure is presented for the simultaneous prediction of fluid–fluid and solid–fluid equilibrium of light gases/heavy hydrocarbons systems under pressure. The objective of this work is to simplify the predictive approach previously proposed by the authors, making it more useful and accessible to users at the petroleum industry. The main modification with respect to the complex LCVM (linear c...

Diamondoids have been of great interest in recent years due to their role in nanotechnology, drug-delivery and medicine. In this review paper we introduce at first the cage nature of diamondoid molecules (polymantanes, adamantologues), the variety of their crystalline lattice structures, the nature of their structural isomers, their stereoisomers, and their other molecular specificities are pre...