a powerful and convenient reaction procedure for the c-n coupling reaction (the buchwald-hartwig reaction), yielding products of n-arylanilines and n-arylamines in both conventional heating and microwave irradiation has been reported. the protocol utilizes a stable and new supper ferromagnetic nanoparticle chelating n-heterocyclic dicarbene palladium(ii) complex (pd-nhc) as catalyst which helps...

A new binuclear paddle-wheel palladium(II) complex of [Pd2(μ-mtzt)4]dmgH2 (1) has been prepared by the treatment of PdCl2 in acetonitrile with mixture of 1-methyl-1H-1,2,3,4-tetrazole-5-thiol (Hmtzt) and dimethylglyoxime (dmgH2) in methanol. Resulted complex was characterized by elemental analysis (CHNS), IR, UV–Vis absorption, 1H NMR spectroscopy and its structure was determined with single-cr...

an efficient synthetic method for successful synthesis of amine denderon on sba-15 and related pd (ii) complex has been developed. this modified mesoporous material was characterized by various techniques such as tem, xrd, atomic absorption spectroscopy, n2 adsorption-desorption, and ft-ir. the catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of al...

the application of the [pd{c6h3(ch2ch2nh2)-4-ome-5-κ2-c,n}(μ-br)]2 complex of 2-methoxyphenethylamine in the heck coupling reaction was considered under both conventional and microwave irradiation conditions, and their results were compared. this complex is an efficient, stable and non-sensitive to air and moisture catalyst for the vinylation of substituted aryl halides with different electroni...

An efficient synthetic method for successful synthesis of amine denderon on SBA-15 and related Pd (II) complex has been developed. This modified mesoporous material was characterized by various techniques such as TEM, XRD, atomic absorption spectroscopy, N2 adsorption-desorption, and FT-IR. The catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of al...

A powerful and convenient reaction procedure for the C-N coupling reaction (the Buchwald-Hartwig reaction), yielding products of N-arylanilines and N-arylamines in both conventional heating and microwave irradiation has been reported. The protocol utilizes a stable and new supper ferromagnetic nanoparticle chelating N-heterocyclic dicarbene palladium(II) complex (Pd-NHC) as catalyst which helps...

the ball and beam system is one of the most popular laboratory setups for control education. in this paper, we design a fuzzy pd cascade controller for a ball and beam system using asexual reproduction optimization (aro) technique. the ball & beam system consists of a servo motor, a grooved beam, and a rolling ball. this system utilizes a servo motor to control ball’s position on the beam. chan...

a new dimeric orthopalladated complex was synthesized via reaction of 2,3-dimethoxy benzaldehyde oxime with palladium chloride and lithium chloride in methanol as solvent and sodium acetate as base at room temperature. the catalytic activity of this dimeric [pd{c6h2(-ch=noh)-(ome)2-2,3}(µ-cl)]2 complex as an efficient, air, and moisture tolerant catalyst was investigated in mizoroki–heck cross ...