Dioxime oxalates are useful precursors for the clean generation of iminyl radicals by sensitised UV photolysis and can be adapted for serviceable preparations of 3,4-dihydro-2H-pyrroles and phenanthridines.

Bimetallic oxalates are a class of layered organic magnets with transition metals M(II) and M'(III) coupled by oxalate molecules in an open honeycomb structure. Energy, structure, and symmetry considerations are used to construct a reduced Hamiltonian, including exchange and spin-orbit interactions, that explains the giant negative magnetization in some of the ferrimagnetic Fe(II)Fe(III) compou...

Chelation is a bonding formed between a metal ion and legend. Chelating improves the absorption of the mineral from the digestive tract. The level of chelated minerals in livestock feeding is typically added at 25-30% of the total mineral in a feed. Chelated minerals have improvement in reproduction, health, soundness and growth. Natural feed with strong chelating properties includes dry melt r...

Introduction Systemic oxalosis is an uncommon condition in which there is a disorder of oxalic acid metabolism producing an accumulation of oxalic acid with subsequent deposition of oxalates in tissues, commonly leading to the development of nephrocalcinosis with an early death from renal failure. The condition is inherited as a recessive disorder and recent studies indicate a failure to conver...

Based on the mechanism postulated for the formation of the cyclic carbonates 3 in the reactions of glycols 1 with oxalyl chloride in the presence of triethylamine, we present here three efficient syntheses of the cyclic oxalates 2 of various glycols 1 by controlling the formation of 3: replacement of the base by pyridine markedly diminishes yields of 3 in all reactions, realizing dramatic rever...

The total, soluble and insoluble oxalate contents of the leaves, stems and buds of Good-King-Henry (Blitum Bonus-Henricus) were extracted and measured using HPLC chromatography. The large, mature leaves contained 42% more total oxalate than in the small leaves and the soluble oxalate content of the large leaves was 33% higher than the smaller leaves. Cooking the mixed leaves, stems and buds in ...