The present fascinating field of research is to synthesize, grow and characterize semi organic NLO crystals. Here an attempt has been made to synthesize and grow number of NLO semi organic crystals. The semi organic crystals posses both the good qualities of host organic material and additive-inorganic material. The crystals grown are amino acidγ-Glycine with additives namely, Potassium Nitrate...

The amphiphillic character, that is, the capacity to simultaneously attract and repel water, has been traditionally reserved to organic molecules such as phospholipids and surfactants, containing both hydrophilic and hydrophobic groups within the same molecule. However, this general concept can be extended to artificial structures such as micrometer-sized particles, the so-called Janus particle...

By the end of the 20th century, the research of electromagnetic behavior of π-electrons in organic crystals made several outstanding achievements. Since 50’s, the epoch-making finding appeared every decade: enhanced conductivity in halogen complexes of aromatic hydrocarbons 1) (1954), highly conductive radical salts of a π-acceptor TCNQ 2) (1960), a charge transfer complex TTF-TCNQ with quasi-o...

Organic single crystals have been well researched for many years. Typical vapor-phase growth of organic crystals developed from vertical to horizontal growth in order to achieve improved crystalline quality. Recently, a field-effect study on these single-crystal semiconductors demonstrated high carrier mobilities, up to ca. 15 cm Vs, along with anisotropic charge-transport properties. These sin...

We present an all-additive manufacturing method that is performed at mild conditions, for the formation of organic single crystals at specific locations, without any photolithography prefabrication process. The method is composed of two steps; inkjet printing of a confinement frame, composed of a water soluble electrolyte. Then, an organic semiconductor solution is printed within the confinemen...

Single-crystal semiconductors have been at the forefront of scientific interest for more than 70 years, serving as the backbone of electronic devices. Inorganic single crystals are typically grown from a melt using time-consuming and energy-intensive processes. Organic semiconductor single crystals, however, can be grown using solution-based methods at room temperature in air, opening up the po...

Fundamental studies of intrinsic charge transport properties of organic semiconductors are often hindered by charge traps associated with static disorder present even in optimized single-crystal devices. Here, we report a method of surface functionalization using an inert non-conjugated polymer, perfluoropolyether (PFPE), deposited at the surface of organic molecular crystals, which results in ...

This work demonstrates that the donor-acceptor-donor charge-transfer chromophores can be tailor-made to be near-infrared absorbing and fluorescent, as well as being liquid crystals. The chromophore containing an extremely strong acceptor of benzo[1,2-c:4,5-c']bis([1,2,5]thiadiazole) can form a columnar mesophase that absorbs at 890 nm and emits at 1160 nm in the solid state. These chromophores ...