The present study investigates the influence of Si on high-temperature corrosion behavior lean FeCrAl model alloys in O2 and O2+H2O at 600 °C. addition prevented breakaway oxidation which may be explained by increased Al-content reduced Cr-content oxide (O2) as well Si-enrichment outer part scale (O2+H2O). A proposed explanation for impact Si-addition Cr- was given thermodynamic calculations sh...

Sodium bisulfite (SBS) is used as an oxygen scavenger to decrease corrosion in pipelines transporting brackish subsurface water used in the production of bitumen by steam-assisted gravity drainage. Sequencing 16S rRNA gene amplicons has indicated that SBS addition increased the fraction of the sulfate-reducing bacteria (SRB) Desulfomicrobium, as well as of Desulfocapsa, which can also grow by d...

As part of the postclosure safety assessment of Ontario Power Generation’s (OPG’s) proposed Deep Geologic Repository (DGR) for Low and Intermediate Level Waste (L&ILW) at the Bruce site, Ontario, a Gas Generation Model (GGM) has been developed and used to model the detailed generation of gas within the DGR due to corrosion and microbial degradation of the organics and metals present. The GGM is...

This paper investigates the effects of dead-ended anode (DEA) operation on the electrode carbon corrosion of the Proton Exchange Membrane (PEM) fuel cell. A reduced order isothermal model is developed focusing on the species concentration along the channel and associated membrane phase potential. This model explains, and can be used to quantify, the carbon corrosion behavior during DEA operatio...

Corrosion of iron and mild steel in gas environments at 550 °C was studied by Gas Phase Analysis (GPA) using 13C16,16O2 18,18O2. This technique is shown to be very powerful identifying gas–metal gas-gas interactions. Mild reacts with O2 oxidize decarburise, CO2 decarburise but not oxidize, CO2/O2 carburise. Using simple kinetic modeling, it demonstrated that the oxidation rate initially control...

Hundreds of tons of depleted uranium (DU) ammunition were used in previous armed conflicts in Iraq, Bosnia and Herzegovina, and Serbia/Kosovo. The majority (>90%) of DU penetrators miss their target and, if left in the environment, corrode in these postconflict zones. Thus, the best way to understand the fate of bulk DU material in the environment is to characterize the corrosion products of in...

In the polymer electrolyte membrane fuel cells (PEMFCs), low corrosion resistance and high interfacial contact resistance (ICR) are two controversial issues in usage of AISI 316L stainless steel as a metallic bipolar plate. For solving these problems, investigation and development of different coatings and/or surface treatments are inevitable. Corrosion behavior and ICR of AISI 316L specimens c...

Reinforcing steel embedded in fresh concrete develops a protective passive layer on its surface. This layer, which is formed as result of high alkalinity of the concrete pore solution (pH~13), consists of γ-Fe2O3 adhering tightly to the steel. As long as that oxide film is present, the steel remains intact [1]. However, chloride ions attack and concrete carbonation can destroy the film and, in ...

In the polymer electrolyte membrane fuel cells (PEMFCs), low corrosion resistance and high interfacial contact resistance (ICR) are two controversial issues in usage of AISI 316L stainless steel as a metallic bipolar plate. For solving these problems, investigation and development of different coatings and/or surface treatments are inevitable. Corrosion behavior and ICR of AISI 316L specimens c...