By proposing a predictive method with no adjustable parameter and by using infinite dilution activity coefficients of components in binary mixtures obtained from UNIFAC model, the binary interaction parameters (k12) in van der Waals mixing rule (vdWMR) and Orbey-Sandler mixing rule (OSMR) have been evaluated. The predicted binary interaction parameters are used in Peng-Robinson-S...

The critical properties of a solute are required for modeling of the solubility by the equation of state. For many compounds, the critical properties are not available. So, group contribution method is utilized as a common method to estimate these properties. But, it leads to the consecutive errors in calculations of the solubility modeling. In this study, Soave-Redlish-Kowang (SRK) and Peng-Ro...

The present study investigates the use of different GE mixing rules in cubic equations of state for prediction of phase behavior of multicomponent hydrocarbon systems. To predict VLE data in multicomponent symmetric and asymmetric mixtures such as systems that contain light gases (nitrogen, carbon dioxide, etc.) and heavy hydrocarbons, the SRK equation of state has been combined with excess Gib...

In this study using Equation of State/ Helmholtz excess energy function,  EOS/AE, two new local composition-Equation-of State mixing rules, LCEOS1 and LCEOS2 were developed in which the energy interaction parameters were expressed in terms of attractive and repulsive parameters of the cubic equation of state. The EOS/AE models are applied for equilibrium calculation of nat...

The neutrino mixing sum rule θ 12 − θ 13 cos(δ) ≈ θ ν 12 provides a possibility to explore the structure of the neutrino mass matrix in the presence of charged lepton corrections, since it relates the 1-2 mixing angle from the neutrino mass matrix, θ ν 12 , to observable parameters of the PMNS mixing matrix. The neutrino mixing sum rule holds if the charged lepton mixing angles are CKM-like, i....

the critical properties of a solute are required for modeling of the solubility by the equation of state. for many compounds, the critical properties are not available. so, group contribution method is utilized as a common method to estimate these properties. but, it leads to the consecutive errors in calculations of the solubility modeling. in this study, soave-redlish-kowang (srk) and peng-ro...

by proposing a predictive method with no adjustable parameter and by using infinite dilution activity coefficients of components in binary mixtures obtained from unifac model, the binary interaction parameters (k12) in van der waals mixing rule (vdwmr) and orbey-sandler mixing rule (osmr) have been evaluated. the predicted binary interaction parameters are used in peng-robinson-stryjek-vera equ...

The q2 dependence of the π-η mixing amplitude is examined with the use of QCD sum rules. The linear slope of the mixing function θ(q2) is found to be much smaller than that for ρ-ω mixing. Thus the mixing amplitude is approximately the same in the space-like region as in the time-like one, and one may neglect the q2 dependence of the mixing. A comparison between a hadron-meson, an effective chi...

A procedure is presented for the simultaneous prediction of fluid–fluid and solid–fluid equilibrium of light gases/heavy hydrocarbons systems under pressure. The objective of this work is to simplify the predictive approach previously proposed by the authors, making it more useful and accessible to users at the petroleum industry. The main modification with respect to the complex LCVM (linear c...