An analysis of neutron diffraction data of liquid deuterated terr-butanol at room temperature to determine its molecular conformation is presented. Being a big molecule of 15 sites, the analysis is tricky and needs careful consideration. The resulting molecular parameters are compared with those obtained from other experimental data analysis and model calculations. The information about the int...

As a continuation of diffraction work on melts from eutectic binary systems such as Al-Sn [1], Au-Co [2], and Bi-Cu [3] an investigation of melts from the eutectic system Sn-Zn by means of neutron diffraction will be described in the present work. The liquidus lines in the constitution diagrams of these systems always show a point of inflection, so th a t segregation tendency in molten state is...

A combined neutron imaging and neutron diffraction facility, IMAT, is currently being built at the pulsed neutron spallation source ISIS in the U.K. A supermirror neutron guide is required to combine imaging and diffraction modes at the sample position in order to obtain suitable time of flight resolutions for energy selective imaging and diffraction experiments. IMAT will make use of a straigh...

X-ray, neutron and electron diffraction methods are widely used for the investigation of crystals. Each of these techniques has their own advantages in terms of element sensitivity, sample size requirements etc. and are chosen accordingly for structure determinations. A less obvious difference lies in the spatial resolution of these diffraction techniques. Here, we show that electron diffractio...

The floating-zone method with different growth ambiences has been used to selectively obtain hexagonal or orthorhombic DyMnO(3) single crystals. The crystals were characterized by x-ray powder diffraction of ground specimens and a structure refinement as well as electron diffraction. We report magnetic susceptibility, magnetization and specific heat studies of this multiferroic compound in both...

We present a detailed study of magnetism in LuFe(2)O(4), combining magnetization measurements with neutron and soft x-ray diffraction. The magnetic phase diagram in the vicinity of T(N) involves a metamagnetic transition separating an antiferro- and a ferrimagnetic phase. For both phases the spin structure is refined by neutron diffraction. Observed diffuse magnetic scattering far above T(N) is...

Seven-membered lactones undergo selective SmI2 -H2 O-promoted radical cyclization to form substituted cyclooctanols. The products arise from an exo-mode of cyclization rather than the usual endo-attack employed in the few radical syntheses of cyclooctanes. The process is terminated by the quenching of a chiral benzylic samarium. A labeling experiment and neutron diffraction study have been used...

Residual stresses generated by macroscopic inhomogeneous plastic deformation are predicted by an explicit finite element (FE) technique. The numerical predictions are evaluated by characterizing the residual elastic strains by neutron diffraction using two different (hkl ) reflections. Intergranular residual elastic strains between subsets of grains are predicted numerically and verified by neu...

The peak profile shape analysis has been preferentially used in evaluation of X-ray and synchrotron powder diffraction pattern. However, neutron diffraction facilities of new generation frequently offer the instrumental resolution high enough to study efficiently the effects of broadening of neutron diffraction profiles. The present paper describes the procedure for a detailed evaluation of Bra...

For large-grained samples it is advantageous to perform pairs of neutron diffraction measurements at the same spatial location but rotated 180° around the geometric centre of the gauge volume as a means of minimizing the scatter coming from the random positioning of grains within the gauge volume.