mg(oet)2 with spherical morphology is one of the most important precursors for the preparation of industrialziegler-natta catalysts. in the present article, morphology evolution of mg(oet)2 particles is studied in the courseof the synthesis. the morphology of mg(oet)2 particles is observed throughout the process by sem. the resultsshow that mg(oet)2 particles are formed through i) seed generati...

a linear low density polyethylene (lldpe) production process, including two- fuidized bed reactors in series (fbrs) and other process equipment, was completely simulated by aspen polymer plus software. fluidized bed reactors were considered as continuous stirred tank reactors (cstr consisted of polymer and gas phases). poly-srk and nrtl-rk equations of state were used to describe polymer and no...

in this article, a complete model for the mixed flow slurry reactor for polymerization of ethylene to high density polyethylene in the presence of ziegler-natta catalyst is presented. in addition to the effects of the multiple active sites, the effect of other important parameters such as the catalyst concentration, co-catalyst, hydrogen, monomer, impurities and pressure on the mass-average and...

in this study, the slurry polymerization of ethylene over ticl4/mgcl2/alet3 was obtained. firstly, to obtain the optimum value of [al]/[ti], the effect of [al]/[ti] on polymerization rate and catalyst yield was studied. also, the effect of catalyst content on yielding, crystallization, melting point and density of product were obtained. to determine the order of reaction, the monomer pressure w...

ethylene was polymerized in slurry phase over a ticl4/mg(oc2h5)2 catalyst activated by al(c2h5)3. it was shown experimentally that mass transfer resistance has no effect on polymerization kinetics. after estimation ofthe active site concentration by inhibition method with carbon monoxide, the effects of polymerization temperature, monomer and cocatalyst  oncentrations and hydrogen were investig...

in the present work, a titanium-based ziegler-natta catalyst was employed to synthesize ultra molecular weight polyethylene in a slurry medium. the effect of different parameters such as ethylene pressure, temperature, catalyst composition, and hydrogen pressure was studied. as the results indicate, increasing either [al]/[ti] ratio or temperature causes polymerization rate to go through a maxi...

copolymerization of ethylene and propylene was investigated using a 4th generation phthalate ziegler-natta catalyst in normal hexane in a buchi reactor. the effects of different mole fractions of [al]/[ti], [si]/[al] and various amounts of hydrogen on productivity and weight percent of ethylene on the product, were studied. in the copolymerization reactions, tri-isobutyl aluminum (tibal) was us...

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The use of UHMWPE has attracted the attention of many researchers and industries. The aim of the present work is to fabricate UHMWPE/MoS2-Oxide nano-composites using in-situ polymerization. For this purpose, modified molybdenum disulfide was used. In order to perform the polymerization, a Ziegler-Natta catalytic system, with MoS2-Oxide and magnesium Ethoxide as support, was used. In order to fa...