nano silica-h2so4 is an efficient and mild catalysis system for the regeneration of aldehyde from aldoximes. ketoximes are converted to amides by beckmann rearrangement in the presence of nano silica-h2so4. the reactions are carried out in solvent-free conditions under microwave irradiation (600 w) within 50-120 sec in good yields.

nano-sbcl5.sio2 and sbcl5.sio2 are bench-top catalysts which are reusable, readily available, versatile andefficient for promotion of many acid catalyzed organic reactions. these catalysts do not need specialprecautions for preparation, handling or storage, and they can be stored at an ambient temperature for monthswithout losing their catalytic activity. 4-dihydropyrimidin-2(1h)-ones(thiones) ...

A study into the effects of amorphous nano-SiO2 particles on A549 lung epithelial cells was undertaken using proteomics to understand the interactions that occur and the biological consequences of exposure of lung to nanoparticles. Suitable conditions for treatment, where A549 cells remained viable for the exposure period, were established by following changes in cell morphology, flow cytometry...

in this study the effect of nano sized silica particles (nano-sio2) on the physical and mechanical properties of rice husk and old corrugated container (occ)-cement boards was investigated. modulus of rupture (mor), modulus of elasticity (moe), internal bonding strength (ib), density, water absorption and thickness swelling after 24 hours immersion in water and hardness were measured. results s...

Choline chloride-malonic acid deep eutectic solvent (Cm-DES) was employed to synthesize Zr0.8Sn0.2TiO4 nano-powders using Zr(CH3COO)4, SnCl2∙2H2O, and Ti(OCH3CH3)4 as raw materials. The nano-powder with the mean grain size of 10.7 nm obtained at 450 °C, significantly lower than that by conventional mixed oxide routes. Meantime, densification ceramics improved as-synthesized powder. relative den...

The interaction between nano-SiO2 and lysozyme was investigated by the method of UV-Visible  detection and fluorescence spectroscopic techniques. The thermal denaturation of lysozyme has been investigated in the presence and absence of nano-SiO2 over the temperature range (293-373) K in different buffers and pH values, using temperature scanning spectroscopy. The presence of nano-SiO2 caused th...

various aldoximes and ketoximes synthesis of corresponding aldehydes and ketones in the presence of sio2@feso4 nano composite as recoverable nano catalyst and nh2oh·hcl. the sio2@feso4 nano composite system was carried out between 10 to 15 min in oil bath (70-80 °c) under solvent-free condition in excellent yields in addition this protocol can be used for industrial scales. this method offers s...

Nanomaterial which has high activity is widely used in the modification of cement-based materials due to its physical filling and chemical bonding. This paper mainly studied the influence of nano-SiO2 on the compressive strength of the alkali-activated materials, using XRD and SEM technology to analyze the mineral composition microstructure of alkali-activated materials, modification effect, et...