in this investigation, nano silica chloride (nano sio2cl) has been found to be efficient, chemoselective and recyclable catalyst for facile and simple synthesis of germinal diacetates from aromatic and heteroaromatic aldehydes in shorter reaction durations. the products were obtained in high to excellent yields. this work consistently has the advantages of excellent yields, short reaction time,...

Multifunctional silica nano-vehicles (SiO2@indol-IL) and magnetic nanoparticles (Fe3O4@indol-IL) were constructed through the Schiff bases condensation of indole-3-carboxaldehyde and 4-acetyl-N-allyl pyridinium chloride (ILs) with the amine groups of silica and magnetic nanoparticles. SiO2@indol-IL can inhibit the proliferation of HepG-2 cells in 48 h. Fe3O4@indol-IL can mimic the function of c...

a novel rice-husk-silica supported n-propyl bipyridinium chloride (rhprbpcl) has been prepared. due to the basicity of rhprbpcl, it was decided to evaluate its catalytic activity in the one-pot preparation of tetrahydrobenzo[b]pyran, dihydropyrano[3,2-c]chromene and dihydropyrano[4,3-b]pyran derivatives. the catalyst was characterized by ft-ir, sem and tga analyses. this methodology offers seve...

Hydrogels, especially double-network hydrogels, are attractive candidates as load-bearing biomaterials, e.g., tissue-engineering supports for articular cartilages and bones. In this study, we describe the modification of a hydrogel by introduction third monomer, N-[3-(dimethylamino)propyl]methacrylamide, to network system, which serves reactive site subsequent interfacial reactions surface-init...

in this study, different contents of nano-silica, 2 wt.%, 4 wt.% and 6 wt.%, have been added to bitumen tomodify the physical, mechanical and rheological properties of warm mix asphalt (wma). wma iscontaining 2 wt.% of sasobit (mixture of long-chain hydrocarbons). various quality control tests have beencarried out to characterize the modified bitumen and wma. the rheological investigations show...