Traces of P(V) and As(V) in sample solutions were converted into heteropoly molybdic acids at pH 1.5 and collected onto polyoxyethylene(20)-4-isononylphenoxy ether-coated Amberlite XAD-4 particles. The desorption was carried out with 0.3 M tetramethylammonium hydroxide solution for the HPLC analysis. Molybdophosphoric and molybdoarsenic acids were separated from excess molybdate by ion-pair rev...

12-molybdophosphoric acid (PMo12) was encaged into HMOR zeolite by “ship in a bottle”method in aqueous phase which is strongly retained and not easily leached from the host channels.The solid was characterized by XRD prior to using it for the electrode preparation. This compoundwas incorporated with a carbon paste electrode for cyclic voltammetric measurements. PMo12immobilized on the support u...

In this paper, we have described the size-controlled synthesis of gold nanoparticles based on the reduction of Au3+ (HAuCl4 ) using molybdophosphoric acid (H3[PMo12O40 ], HPMo) under UV-irradiation. In the process, HPMo plays the role of photocatalyst, reducing agent and stabilizer and propan-2-ol acts as a sacrificial agent. This method allows the synthesis of uniform hexagonal nanoparticles w...