We report the photocatalytic oxidation of benzylic carbon atoms under mild conditions using riboflavin tetraacetate as photocatalyst and blue-emitting LEDs (440 nm) as light source. Oxygen is the terminal oxidant and hydrogen peroxide appears as the only byproduct in most cases. The process oxidizes toluene derivatives, stilbenes, styrenes and phenylacetic acids to their corresponding benzaldeh...

The Fourier transform infrared (FTIR) and Raman spectra of 2-amino-4-nitrotoluene; 2-amino-5-nitrotoluene; 2,4-dimethylaniline; 2,5-dimethylaniline; 2,6-dimethylaniline; 1,2,4-trimethylbenzene; 1,3,5-trimethylbenzene and pentamethylbenzene have been recorded in the range 4000-400 cm(-1) and 4000-30 cm(-1), respectively. A normal coordinate analysis was carried out for both in-plane and out-of-p...

Toluene-o-xylene monooxygenase is an enzymatic complex, encoded by the touABCDEF genes, responsible for the early stages of toluene and o-xylene degradation in Pseudomonas stutzeri OX1. In order to identify the loci involved in the transcriptional regulation of the tou gene cluster, deletion analysis and complementation studies were carried out with Pseudomonas putida PaW340 as a heterologous h...

In this study we have investigated the possibility of processing waste rubber gloves using pyrolysis. Y-zeolite catalyst was employed to upgrade the pyrolysis products to give higher yields of valuable aromatic compounds such as toluene and xylenes. The composition of the pyrolysis products was determined using gas chromatography with linked mass spectrometry (GC-MS), gas chromatograph equipped...

• ERI-type molecular sieves enhance ethylene selectivity in MTO . Acidity significantly influences ethylene-to-propylene ratio materials. Changes acidity alter hydrocarbon-pool species concentration and composition. Low acid site densities hinder the formation of aromatics (thus, ethylene) ERI. (SSZ-98, UZM-12, zeolite, SAPO-17) are synthesized with varying Si/Al = 5–9 Si/T-atoms 0.034–0.12 usi...

Coal tar is obtained by cooling the gas that is formed during the destructive distillation of coal to approximately ambient temperature. It is a black, viscous liquid composed primarily of a complex mixture of condensed-ring aromatic hydrocarbons. It may contain phenolic compounds, aromatic nitrogen bases and their alkyl derivatives, and paraffinic and olefinic hydrocarbons. Coal-tar pitch is t...