Conventionally, methane is reformed into syngas, and subsequently converted into C1-oxygenates (methanol and formaldehyde). A novel option is the catalyst-free single-step conversion of methane to C1-oxygenates. This study presents a comprehensive model of methane partial oxidation to formaldehyde as an intermediate chemical species in methane oxidation process using microreactor. The dependenc...

A novel method for the study of non-oxidative methane conversion process into higher value hydrocarbon and hydrogen has been invented. The method involves the multiphoton dissociation of methane under the influence of the high power pulsed ultraviolet laser radiation at 355 nm wavelength at room temperature (293 K) and standard pressure (1 atm). The products generated as a result of methane con...

the direct conversion of methane to c2 hydrocarbons, in a quartz tube reactor enforced by a dc corona discharge, was investigated at atmospheric pressure. the process was carried out in the presence of metal oxide catalysts of mn/w/sio2, mn/w/sio2 (tetraethyl orthosilicate, teos), and mn/w/cnt (supported on carbon nanotubes). the total yield to c2 hydrocarbons in the presence of metal oxide cat...

Dry reforming of methane (DRM) has been investigated under an electronactivated catalytic bed in a thermo-electrical reactor. The main objective of this work was to investigate what the impact of the electrical current on the conversion of methane is. The combination of thermal and electrical energy allowed achieving higher conversions for both reactants at temperatures varying from 850–950°C. ...

Efficient Solid waste utilization is a challenging task. In rural areas organic wastes like cattle waste is available in abundant, which is not utilized in the valuable forms and in urban areas it is disposed off in an improper manner. In this study biogas primarily from cattle waste was generated by using a fabricated anaerobic biogas digester. The methane is easily separated from biogas by re...

The activity of different transitional metals over modified H-ZSM-5 catalysts for methane conversion to aromatics was compared. The first group of catalysts was Mo-impregnated H-ZSM-5 zeolites with 1, 3 and 6 wt% of Mo. The second group was M(3 wt%)- impregnated H-ZSM-5 (M: Ag, Cd, Cr, Mo, Zn and Mn). The catalytic activity of the first group was investigated at 600, 700 and 800 °C and gas hour...

The combustion characteristics of methane/moist air in micro-tube reactors with different numbers and shapes of inner wall protuberances are investigated in this paper. The micro-reactor with one rectangular protuberance (six different sizes) was studied firstly, and it is shown that reactions near the protuberance are mainly controlled by diffusion, which has little effect on the outlet temper...

An alumina-supported nickel catalyst was prepared by impregnation of Ni2+ solution onto mesoporous alumina under microwave irradiation (denoted as M-Ni/Al2O3). For comparison, a catalyst with the same nickel content was prepared by conventional impregnation method (denoted as UM-Ni/Al2O3). Both M-Ni/Al2O3 and UM-Ni/Al2O3 catalysts were applied to the syngas (H2 + CO) production by methane oxy-s...