Atomically dispersed metal catalysts are interesting materials for electrocatalysis. To this end, covalent organic frameworks (COFs) offer an excellent opportunity the periodic placement of catalytically active single atoms within a porous framework. We report here synthetic strategy to series imide-linked metal-containing phthalocyanine (Pc) COFs with different contents. Electrocatalytic activ...

The use of hydrogen peroxide as a precursor to improvised explosives has made its detection a topic of critical importance. Chemiresistor arrays comprised of 50 nm thick films of metallophthalocyanines (MPcs) are redox selective vapor sensors of hydrogen peroxide. Hydrogen peroxide is shown to decrease currents in cobalt phthalocyanine sensors while it increases currents in nickel, copper, and ...

The gas-surface reaction dynamics of NO impinging on an iron(II) phthalocyanine (FePc) monolayer were investigated using King and Wells sticking measurements. The initial sticking probability was measured as a function of both incident molecular beam energy (0.09-0.4 eV) and surface temperature (100-300 K). NO adsorption onto FePc saturates at 3% of a monolayer for all incident beam energies an...