in this paper, macrocyclic cobalt(ii) complexes [col1](no3)2.4h2o (1) and [col2](no3)2.2h2o (2) have been synthesized from the reaction of dialdehydes 1,2-bis(2-formylphenyl)ethane and 1,3-bis(2-formylphenyl)propane, co(no3)2.6h2o and 1,2-cyclohexanediamine with molar ration 1:1:1 in methanole and characterized by elemental analyses and ft-ir spectroscopy. then used as precursors for preparatio...

Ultrathin nanocomposite films were prepared on solid supports via adsorption of organic and inorganic molecules from solution. Coordination geometry for transition metal ions was preserved by embedding metal ligands into titanium oxide gel films, and porous titanium oxide films were prepared by selective removal of organic components from polymer/metal oxide composite films using oxygen plasma ...

introduction: nanoparticles are being increasingly applied in dentistry due to their antimicrobial and mechanical properties. this in vitro study aimed to assess and compare the cytotoxicity of four metal oxide nanoparticles (tio 2 , sio 2 , zno, and al 2 o 3 ) on human dental pulp stem cells. methods and materials: four suspension with different concentrations (25, 50, 75, 100 µg/ml) of each n...

copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [cu3(btc)2] (1) and [cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400,  500, and 600°c. it has also been found that the reaction temperature pla...

metal-organic frameworks (mofs) represent a new class of highly porous materials. on this regard,  two nano porous metal-organic frameworks of [zn2(1,4-bdc)2(h2o)2∙(dmf)2]n (1) and [zn2(1,4-bdc)2(dabco)]·4dmf·1⁄2h2o (2), (1,4-bdc = benzene-1,4-dicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]octane and dmf = n,n-dimethylformamide) were synthesized and characterized. they were used for preparation ...

Mesoporous silica metal oxide (ZnO and CdO) thin films have been used as metal ion precursors to produce the first examples of mesoporous silica metal sulfide (meso-SiO(2) @ZnS, meso-SiO(2) @CdS) or silica metal selenide (meso-SiO(2) @ZnSe, meso-SiO(2) @CdSe) thin films, in which the pore walls are made up of silica and metal sulfide or metal selenide nanoflakes, respectively. A gentle chemical...

Well-ordered, thin oxide films have drawn some attention in recent years as suitable oxide supports for modeling highly dispersed metal catalysts at the atomic scale. It turned out, however, that ultrathin oxide films may exhibit interesting catalytic properties in their own right. In this review, we discuss phenomena specifically connected to ultrathin oxide films to explain and understand the...

We have developed a corrosion model that can predict metal oxide growth and dissolution rates as a function of time for a range of solution conditions. Our model considers electrochemical reactions at the metal/oxide and oxide/solution interfaces, and the metal cation flux from the metal to the solution phase through a growing oxide layer, and formulates the key processes using classical chemic...

Recently, the rapid emergence of antibiotic-resistant pathogens has caused a serious health problem. Scientists respond to the threat by developing new antimicrobial materials to prevent or control infections caused by these pathogens. Polymer-based nanocomposite hydrogels are versatile materials as an alternative to conventional antimicrobial agents. Cross-linking of polymeric materials by met...

Hollow metal oxide nanocrystals were prepared by etching cuprous oxide with metal ions and were applied as photoelectrodes. As a hard template, polyvinylpyrrolidone stabilized cuprous oxide (PVP-Cu2O) and non-stabilized cuprous oxide (nPVP-Cu2O) were synthesized by a precipitation method. Hollow iron oxide and cobalt oxide nanocrystals with a truncated octahedral morphology were fabricated by a...