نتایج جستجو برای: macroinitiator

تعداد نتایج: 77  

2014
Yesim Hepuzer Gursel Ayfer Sarac Bahire Filiz Senkal

A poly(ethylene glycol) (PEG) based macroinitiator (MI) with terminal chloride atom at both ends was prepared by the reaction of PEG-400 with chloroacetyl chloride and used for the cationic polymerization of dodecyl vinyl ether (DVE) yielding ABA type block copolymer. The block copolymer was then used as the surfactant for the emulsion polymerization of vinyl acetate and styrene in the presence...

Journal: :Macromolecular rapid communications 2011
Jiayin Yuan Niels ten Brummelhuis Mathias Junginger Zailai Xie Yan Lu Andreas Taubert Helmut Schlaad

Commercially available 1,2-PB was transformed into a well-defined reactive intermediate by quantitative bromination. The brominated polymer was used as a polyfunctional macroinitiator for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline to yield a water-soluble brush polymer. Nucleophilic substitution of bromide by 1-methyl imidazole resulted in the formation of polyelectrolyte c...

2017
Camila Franco Michelli Barcelos Antonow Aline Beckenkamp Andréia Buffon Taise Ceolin Marli Luiza Tebaldi Gustavo Pozza Silveira Silvia Stanisçuaski Guterres Adriana Raffin Pohlmann

The data presented here are related to the research paper entitled "PCL-b-P(MMA-co-DMAEMA)2 new triblock copolymer for novel pH-sensitive nanocapsules intended for drug delivery to tumors" by Franco et al. [1]. Characterization data of PCL-diol, macroinitiator Br-PCL-Br, homopolymers (PMMA and PDMAEMA) and copolymers (batch 1 and batch 2) analyzed by FTIR, SEC and NMR, as well as, characterizat...

Journal: :Membranes 2015
Alsu A Akhmetshina Ilsiya M Davletbaeva Ekaterina S Grebenschikova Tatyana S Sazanova Anton N Petukhov Artem A Atlaskin Evgeny N Razov Ilnaz I Zaripov Carla F Martins Luísa A Neves Ilya V Vorotyntsev

Microporous polymers based on anionic macroinitiator and toluene 2,4-diisocyanate were used as a support for 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF₆]) and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([emim][Tf₂N]) immobilization. The polymeric support was modified by using silica particles associated in oligomeric media, and the influence of the modifier us...

Journal: :ACS applied materials & interfaces 2013
Juan C Tuberquia G Kane Jennings

We introduce the use of a hydroborated polyisoprene (PIP) macroinitiator for the rapid surface-initiated growth of superhydrophobic polymethylene (PM) films. Rinsing of a dip-coated PIP film on a methyl-terminated surface atop silicon or gold substrates results in robustly bound, isolated PIP clusters. After hydroboration of the internal olefins, these clusters result in extremely rapid growth ...

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