Liquid–liquid equilibrium (LLE) data are critical for the design and optimization of processes extracting aromatics. Partial LLE non-aromatic–aromatic–sulfolane ternary system were acquired at 313.15 K 101.3 kPa. The extraction aromatics using sulfolane predicted COSMO-RS model. Correspondingly, experimental analyzed root mean square deviation (RMSD), distribution coefficient (D), separation fa...

Sulfolane is an emerging industrial pollutant detected in the environments near many oil and gas plants North America. So far, numerous advanced oxidation processes have been investigated to treat sulfolane aqueous media. However, there only a few papers that discuss degradation of using photocatalysis. In this study, photocatalytic titanium dioxide (TiO2) reduced graphene oxide TiO2 composite ...

Polyacrylonitrile (PAN) gel was prepared by the freezing and thawing method using the solvents of N,N-dimethylacetamide (DMA) and tetramethylene sulfone(sulfolane). The gelation time after a series of freezing and thawing was examined with varying PAN concentration of DMA solution and the freezing time. Dynamic viscoelasticity was measured in the course of gelation for DMA solution to observe t...

The focus of this paper was to identify a cheaper solvent from among diesel fuel, kerosene, sulfolane or a mixture of sulfolane and cyclohexanol for the preparation of cyanuric acid heterocyclization of urea. To obtain a higher yield, the effects of catalyst (sodium, ammonium, calcium and zinc salts) and temperature (160 degrees C to 220 degrees C) on the trimerization of urea were also careful...

Recently sulfolane has been detected in well water within the town of North Pole, Alaska. A plume was identified in groundwater, originating from a petroleum refinery, and the highest concentration measured in wells outside the refinery was 269 ppb as of January 2011. Due to the contamination, residents were being provided bottled water for use and additional wells were created outside the plum...

Described is a GC-MS method for the determination of the levels of sulfolane (tetrahydrothiophene 1,1-dioxide, C4H8O2S; a water miscible chemical used in the sweetening of sour gas) in wetland vegetation (roots, shoots, berries, seeds, grasses, and leaves). The technique was developed to provide positive detection of sulfolane in a variety of wetland vegetation and to determine the extent to wh...

Co(II)-based metalloradical catalysis has, for the first time, been successfully applied for asymmetric intramolecular C–H alkylation of acceptor/acceptor-substituted diazo reagents. Through the design and synthesis of a new D2-symmetric chiral amidoporphyrin as the supporting ligand, the Co(II)-based metalloradical system, which operates at room temperature, is capable of 1,5-C–H alkylation of...