steel slags are the by products of steel industries, which forms during reduction process of iron melting. the chemical composition of it changes depending to the melting procedure. its mineralogical composition also varies based on the cooling procedure. two different types of steel slag were used as absorbing bed for various concentrations of pb2+ ions in the form of lead chloride, and the co...

The present study was aimed at the estimation of heavy metal content in vegetables sold at the city market of one of the densely populated Croatian cities, Varaždin, and to establish the relationship between their levels and possible sources of contamination. Twenty-eight samples of the most common diet vegetables (red and white potato, onion, carrot, common bean, lettuce, and cabbage) were ran...

Direct measurement of lead and cadmium in blood and urine by electrothermal atomic absorption spectrometry with deuterium background correction (D2-AAS) is prone to severe matrix and spectral interferences. We overcame these effects by coating the L'vov platform with ammonium molybdate, reducing the atomization time, introducing a post-atomization cooling step, carefully selecting ashing and at...

Aim of this study was to determine concentration of Pb, Cd, As and Hg in green leafy vegetables and soil in the urban area of Zagreb, Croatia and to determine if there is a connection between the contamination of soil and vegetables. Green leafy vegetables and soil samples were taken from the gardens located in the outskirts of the city. Concentrations of Pb, Cd, As and Hg were determined by at...

background soil pollution due to toxic metals released by industrial activities such as cement production is a serious problem from the standpoints of the environment and public health, because they tend to persist, circulating indefinitely and, eventually, accumulating throughout the food chain. objectives this paper presents the results of the first research study into the distribution of cad...

Perovskite-based solar cells have recently been catapulted to the cutting edge of thin-film photovoltaic research and development because of their promise for high-power conversion efficiencies and ease of fabrication. Two types of generic perovskites compounds have been used in cell fabrication: either Pb- or Sn-based. Here, we describe the performance of perovskite solar cells based on alloye...

A fast ultrasound-assisted sequential extraction (UASE) procedure for the determination of cadmium, lead and nickel fractions in soil was developed and fully validated. The working parameters of an ultrasound probe were optimized by comparing the content of metals in soil extracts obtained by the UASE procedure with that obtained by the conventional (with the aid of a vertical rotor) modified C...

We present a comprehensive theoretical investigation of the light absorption rate at a Pb/Ge(111)-β√3 × √3R30° surface with strong spin-orbit coupling. Our calculations show that electron spin-flip transitions cause as much as 6% of the total light absorption, representing 1 order of magnitude enhancement over Rashba-like systems. Thus, we demonstrate that a substantial part of the light irradi...

The aim of this study was the occupational exposure assessment to lead and manganese of workers in an armament repair shop of a military organization. The air of the working environment was assessed in the environmental monitoring while the internal dose biological indicators for lead and manganese, in blood and urine, were used in biological monitoring. Metals concentration in filters and biol...