Cobalt-based perovskite catalysts showed excellent performance towards NO-NO2 oxidation. We systematically investigated the influence of different levels of Cu-doping on the catalytic performance of hexagonal phase LaCoO3 (LaCo1-xCuxO3 (x = 0.1, 0.2, 0.3)) for NO oxidation. The catalytic activities of the oxide catalysts followed the sequence: LaCo0.9Cu0.1O3 > LaCoO3 > LaCo0.8Cu0.2O3 > LaCo0.7C...

Charge-transfer-induced intrinsic multivalent states in LaCoO3/SrTiO3 heterostructures are demonstrated by Xuefeng Wang, Wenqing Liu, Yong Pu, and co-workers article number 2000803. Interactions of these ions contribution to emergent ferromagnetism. Beyond LaCoO3/SrTiO3, a more broad charge-transfer scenario with resultant multivalence or conducting interfaces is established, constituting power...

Manipulating the orbital state in a strongly correlated electron system is of fundamental and technological importance for exploring and developing novel electronic phases. Here, we report an unambiguous demonstration of orbital occupancy control between t2g and eg multiplets in quasi-two-dimensional transition metal oxide superlattices (SLs) composed of a Mott insulator LaCoO3 and a band insul...

in this paper, labo3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. lacoo3 perovskite formulation showed the highest activity among labo3 (fe, mn and co) perovskite catalysts. so, lacoo3 perovskite based catalyst was s...

Single-phase powders of LaMnO3 and LaCoO3, lanthanum-based perovskites, were synthesized using the citric acid combustion method. The surface concentration La in obtained powder was higher LaCoO3 than LaMnO3. These samples decomposed 2-naphthol water dark. decomposition reaction is attributed to Mars–van Krevelen (MvK) mechanism because temperature dependence, activation energy, valence change ...

– An impurity-driven magnetic phase transition has been investigated in LaCoO3 at temperatures below that of the thermally induced spin state transition of the Co ion. We have discovered a saturating component of the magnetisation, which we attribute to previously unobserved interactions between magnetic excitons. These conclusions are confirmed by muon spin spectroscopy which indicates an orde...

In this paper, LaBO3 perovskite type catalyst formulations were prepared by sol-gel auto combustion method using citric acid as the fuel. Activity of catalysts was tested in catalytic oxidation of toluene as a model of volatile organic compounds. LaCoO3 perovskite formulation showed the highest activity among LaBO3 (Fe, Mn and Co) perovskite catalysts. So, LaCoO3 perovskite based catalyst was s...

NdCoO3, and LaCoO3, are strikingly similar to each other and to RCo03 where R (6) is the natural rare earth mixture as mined. We suggest, therefore, that the unseparated rare earth oxides can be used to make a cheap auto exhaust oxidation catalyst. LEE A. PEDERSEN W. F. LIBBY Department of Chemistry and Institute of Geophysics and Planetary Physics, University of California, Los Angeles 90024 R...