in this work, based on experimental observations and exact theoretical predictions, the kinetic scheme of raft polymerization is extended to a wider range of reactions such as irreversible intermediate radical terminations and reversible transfer reactions. the reactions which have been labeled as kinetic scheme are the more probable existing reactions as the theoretical point of view. the deta...

kinetic parameters of the ammonolysis reaction of dichloroethane in nonaqueous media are studied and the optimum reaction conditions are reported. a suitable reactor for running the reaction under high pressure in the range of 50 to 500 °c is designed. kinetic behaviours of the system is studied and other reaction parameters such as rate constant, kinetic order, and activation energy are determ...

we reduce the two phase stefan problem with kinetic to a system of nonlinear volterra integral equations of second kind and apply newton's method to linearize it. we found product integration solution of the linear form. sufficient conditions for convergence of the numerical method are given and their applicability is illustrated with an example.

The pseudo-first order rate constants and activation parameters have been determined using two methods, constant-temperature kinetic (CTK) and variable temperature kinetic (VTK), for the oxidative addition reactions of [Pt2Me2(C^N)2(µ-dppf)], (1a, C^N = deprotonated 2-phenylpyridine (ppy); 1b, C^N = deprotonated benzo[h]quinoline (bhq)) with MeI. The results obtained from VTK method are in agre...

This minisymposium focuses on recent advances on efficient and accurate numerical methods for PDEs and their various applications in physical or biological systems. The invited researchers will discuss a wide range of computational methods ranging from efficient finite element and finite difference methods, adaptive methods, multiscale methods, to spectral methods and kinetic Monte Carlo simula...