To further understand the effect of chrome tanning on the thermal stability of leather, the thermal shrinkage behaviors of native and chrome-tanned collagen fibers were studied by differential scanning calorimetry (DSC) using isoconversional and multivariate non-linear regression (Multivar-NLR) methods. The activation energies of the shrinkage processes were evaluated by both the differential (...

An isoconversional modeling approach has been considered in the modeling of heat transfer and pyrolysis in a charring material. The isoconversional approach is appealing due to the use of only a single reacting component as opposed to the multicomponent model typically used. This reduces the number of required field variables which reduces numerical demands in large multi-dimensional models. In...

In the present research, the primary crystallization kinetics of the amorphous Fe85.3B11P3Cu0.7 alloy was analyzed using non-isothermal DSC measurements. The average and local activation energies, Ea, were determined by different isokinetic and isoconversional methods. The results obtained for activation energy in this research, show that due to the complexity of the primary crystallization pro...

Isoconversional analysis is a model-free and powerful approach that readily provide quantitative information of the kinetics thermally activated transformation. Activation energy preexponential factor are main output isoconversional analysis. Another practical application kinetic predictions computed in way. In this communication, computational tool predicting nonisothermal presented. This dire...

The objective of this work is to obtain the thermodynamic parameters (the changes in enthalpy, Gibbs free energy, and entropy) two degradation steps observed three novel families organometallic dendrimers. isoconversional Flynn–Wall–Ozawa (FWO) model was employed calculate effective activation energy pre-exponential factor. enthalpy entropy revealed a quite consistent tendency with whereas chan...