Laser parameters, typically wavelength, pulse width, irradiance, repetition rate, and pulse energy, are critical parameters which influence the laser ablation process and thereby influence the LA-ICP-MS signal. In recent times, femtosecond laser ablation has gained popularity owing to the reduction in fractionation related issues and improved analytical performance which can provide matrix-inde...

This application note describes a robust analytical method for the determination of heavy metals and substances regulated by the EU Restriction of Hazardous Substances/End of Life Vehicles (RoHS/ELV) directives. Based on the experience of Nihon Environmental Services Co., Ltd in Japan using an Agilent Technologies 7500c ORS (Octopole Reaction System) collision/reaction cell ICP-MS, this note su...

A home-made system hyphenating capillary electrophoresis with an inductively coupled plasma mass spectrometer (CE-ICP-MS) for cadmium speciation of protein-binding and free cadmium ions in solution is presented. The CE-ICP-MS interface consisted of an acrylic block with an internal volume ca. 20 microL in which a platinum electrode, a capillary column, and a connection to an ICP nebulizer were ...

The laser ablation (LA) method is an effective technique for quantitative analysis. In the present work, a new LA system was developed for the high-sensitivity analysis of metal materials using inductively coupled plasma mass spectrometry (ICP-MS). This system consists of a high-frequency Q-switched laser and 2 scanning mirrors for scanning the ablation spot in an adequately large area of the s...

Inductively coupled plasma-mass spectrometry (ICP-MS) is the method of choice for analysis of most elements across the periodic chart. Its multi-element capability, low detection limit (ppt), and wide dynamic range (109 orders of magnitude) also make it ideal for the measurement of inorganic engineered nanoparticles (ENPs). While ICP-MS can be used directly to obtain concentrations of nanoparti...

Nafion-coated bismuth film electrodes (NCBFEs) and Nafion-coated mercury film electrodes (NCMFEs) were used to electrochemically preconcentrate metal analytes for subsequent analysis by inductively coupled plasma-mass spectrometry (ICP-MS). Either type of electrodes is part of a thin-layer electrochemical flow cell that is positioned upstream of a microconcentric nebulizer for the ICP-MS. Perfo...

Through analysis of their chemical composition, human teeth may serve as retrospective bioindicators of preand postnatal nutrition and exposures to environmental pollutants. The research presented here explores the agreement of laser ablation ICP-MS and solution ICP-MS analyses aimed at capturing temporal changes in the trace element composition of enamel. Good agreement was found for LA-ICP-MS...