Following our previous studies on potassium poly(heptazine imide) (K-PHI), that is, catalyzed photooxidative [3+2] aldoxime-to-nitrile addition to form 1,2,4-oxadiazoles, we discovered electron-rich oximes yield the parent aldehydes instead of target products. In this work, mechanism singlet oxygen-mediated deoximation process was established using a series control reactions and spectroscopic m...

Oximes were oxidized to the corresponding carbonyl compounds in good to high yields by ecofriendlyand green oxidant, H202 catalyzed by Montmorillonite K-10 supported Mangenese(II)Chloride. The structures of these compounds were favorably compared with the results of ab initiocalculations at three temperatures. Computational methods allow for the visualization of largeamounts of structural data ...

oximes were oxidized to the corresponding carbonyl compounds in good to high yields by ecofriendlyand green oxidant, h202 catalyzed by montmorillonite k-10 supported mangenese(ii)chloride. the structures of these compounds were favorably compared with the results of ab initiocalculations at three temperatures. computational methods allow for the visualization of largeamounts of structural data ...