crosslinked poly(acrylic acid)s were prepared using two types of crosslinker by precipitation polymerization method in a binary organic solvent. n,n’-methylenebisacrylamide (mba) and polyethylene glycol dimethacrylate (pegdma-330) were used as low-molecular weight and long-chain crosslinkers, respectively. the effect of various types of crosslinkers on polymer characteristics (i.e., gel content...

showing the occurrence of glass/rubber transition in bovine serum albumin (a globular protein) atlow moisture levels and the occurrence of maillard crosslinking in gelatin in previous works, the importanceof the state of glass or rubber of bsa on the rate and extent of polymerisation, protein solubility, colour andsds page patterns in the presence and absence of ascorbic acid, diketogulonic aci...

Different equations have been proposed for estimating the glass transition temperature of amorphous mixtures. All such expressions lack a term to account for the effect of the entropy of mixing on the glass transition. An entropy based analysis for the glass transition of amorphous mixtures is presented. The treatment yields an explicit mixing term in the expression for the glass transition tem...

4-chloromethyl styrene (cms) was copolymerized with different monomers such as methyl methacrylate (mma), methyl acrylate (ma), 2-ethylhexyl acrylate (eha) by free radical polymerization method at 70 ±1°c using a,a'-azobis(isobutyronitrile) (aibn) as an initiator. the copolymer compositions were obtained using related 1hnmr spectra and the polydispersity of the copolymers were determined using ...

It is very important in the design of a drying system is to evaluate sticking behaviour of the materials goes under drying. A new approach to the sticking issue is applied in this study by carrying out a sticking test for the liquid associated with the materials under study. It was found that the liquid bridge is responsible of the initial sticking of the materials to the contact surface and th...

We present some numerical results for the Heisenberg spin-glass model with Gaussian interactions, in a three-dimensional cubic lattice. We measure the ac susceptibility as a function of temperature and determine an apparent finite temperature transition which is compatible with the chiral-glass temperature transition for this model. The relaxation time diverges like a power law t,sT−Tcd with Tc...

The nonlocal viscosity kernels of polymer melts have been determined by means of equilibrium molecular dynamics upon cooling toward the glass transition. Previous results for the temperature dependence of the self-diffusion coefficient and the value of the glass transition temperature are confirmed. We find that it is essential to include the attractive part of the interatomic potential in orde...

Birefringence of oxide glass bers drawn from glass melts through an ori ce has been detected previously [1, 2]. This birefringence is a measure of anisotropy in glass structure that can in uence ber performance properties. Birefringence is produced during ber drawing as the ber is rapidly stretched in the viscoelastic glass transition range. The birefringence is \frozen" into the glass during r...

The glass transition behaviour of the four metallic glasses La55Al25Ni20 , Zn65Mg35, and Nd60Fe30Al10 and Zr30Y30Al15Ni25 has been studied by temperature-modulated di€ erential scanning calorimetry (MDSC). It is clearly demonstrated that the glass transition can be separated from crystallization by MDSC. Two glass transitions have been observed for Zn65Mg35, Nd60Fe30Al10 and Zr30Y30Al15Ni25. Ow...