نتایج جستجو برای: free energy activation
تعداد نتایج: 1525654 فیلتر نتایج به سال:
thin layer drying of russian olive (elaeagnusan gastifolial l.) fruit using a hot air dryer in order to calculate effective moisture diffusivity, activation energy and energy consumption has been evaluated in this article. the selected variables included three levels of air velocity of 0.5, 1 and 1.5 m/s and three air temperature levels of 50, 60 and 70°c. increased air temperature increased ef...
the 1h and natural-abundance 13c-nmr spectra of 1-thiacyclooctan-3-one (1) have been measured from 25 to -100°c. coalescence is observed in the 1h-nmr spectra of (1) at about -80°c, and attributed to ring inversion in a boat-chair conformation, which is the predominant conformation of (1). the free energy of activation (dg¹) for this process is 9.2±0.2 kcal/mol. the 13c-nmr spectra of (1) is te...
cotton fibres were subjected to cleaning process and then characterized for maturity. decrystallisation and swelling processes with caustic soda, ethanol, propan-2-ol and trichloroethene on the native fibres were carried out. the effects of these on the strength and moisture regain were investigated. the activation energies of the dyeings were also analysed with durazol scarlet red 4 bas. the r...
poly(ethylene adipte) and poly(ethylene adipate)/silica nanocomposite (pead/sio2) containing 3 wt. % sio2 were prepared by an in situ method. the examinations on the non-isothermal crystallization kinetic behavior have been conducted by means of differential scanning calorimeter (dsc). the avrami, ozawa, and combined avrami and ozawa equations were applied to describe the crystallization kinet...
One of the decisive factors in obtaining the desired properties in coatings is their complete curing, which necessitates the study of kinetics of curing. In recent years, many studies have been conducted on the use of polyhedral oligomeric silsesquioxane (POSS) in coatings. Creating functional groups on POSS and using it in formulation can create new or improve the properties of coatings. I...
Determine the lifetime of explosive chemicals is one of the important research fields in recent years. Among the various methods of estimating life expectancy, methods based on solid-state kinetic analysis of the thermal decomposition of a chemical explosive are scientific and the accuracy of the method is confirmed. In this study, the determination of kinetic parameters of Ocfol explosive was ...
Isothermal redox kinetics of as-received Co3O4 (AC), 1 h ball milled Co3O4 (BC), and 1 h ball milled Co3O4-15wt.% Fe2O3 (BCF) was investigated at various temperatures (1130, 1100, 1070, and 1040 °C for reduction and 830, 860, and 890°C for re-oxidation) by thermogravimetric method. It was found that mechanic...
PBXN-111 is a cast cured underwater explosive containing RDX, ammonium perchlorate, aluminium powder and HTPB binder. In this research, the kinetics and thermodynamic properties of thermal decomposition of this PBX investigated by Kissinger and Flynn-Wall-Ozawa (FWO) methods based on differential scanning calorimetry under non-isothermal condition with heating rate of 5, 10, 15 and 20 °C/mi...
in this thesis protic and aprotic ammonium-based ionic liquids were synthesized and their surface tensions were measured in the range of 298-373k. the protics are alkyl ammonium-based ils with the carboxylate (formate, acetate, propionate) anion and aprotics are quaternary ammonium-based ils with bis(trifluoromethylsulfonyl)imide anion. capillary rise method was used for surface tension measure...
In this study, reactions of the simple cycloalkynes with substituted Nitrile Oxides, by DFT method will be discussed. The investigation of the structural properties, theoretical thermodynamic and kinetic data, i.e., the activation free energies(DG*), the free energies changes of reaction(DrG) and rate constants of the reactions (k) in 298 K and effects of Electron-withdrawing and...
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