In this method of analysis for selenium in whole blood by flameless atomic absorption spectrophotometry, 1 mL of sample is first digested with perchloric and nitric acids. After reduction and neutralization, the sample is reacted with 2,3-diaminonaphthalene, and the product is extracted into toluene. Twenty microliters of the extract is injected into the graphite furnace of a flameless atomic a...

This paper performs calculations of the recirculation factor in simulations of a flameless combustion furnace with different percentages of oxygen in air (from 21% to 100% O2). Results are compared with Magnussen’s recirculation theory and show that when there are chemical reactions, the recirculation results are overpredicted. An alternative correlation to Magnussen’s theory is proposed, usefu...

Because of the large quantities of venous blood required, assays of total iron-binding capacity (TIBC) and serum iron are often omitted in diagnostic tests involving small children. As an alternative to the conventional method of assessing TIBC, we developed a micromethod based on flameless atomic absorption spectrophotometry (flameless AAS). Additionally, the standard microproc#{233}dure for d...

We introduce the hybrid functional HSEsol. It is based on PBEsol, a revised Perdew-Burke-Ernzerhof functional, designed to yield accurate equilibrium properties for solids and their surfaces. We present lattice constants, bulk moduli, atomization energies, heats of formation, and band gaps for extended systems, as well as atomization energies for the molecular G2-1 test set. Compared to HSE, si...

When the high power ultrasound irradiates the liquid, small liquid droplets are generated from the liquid surface. This phenomenon is called as ultrasonic atomization [1]. Recently, it has been reported that ethanol is concentrated from the aqueous solution by ultrasonic atomization [2-4]. Since ultrasonic atomization scarcely accompanies the phase change, this is a great advantage comparing wi...

Electrothermal atomic absorption spectrometry has five major advantages for measurements of trace metals in biological materials, in comparison to measure­ ments by conventional flame atomic absorption analysis: (1) Trace metal contami­ nation is minimized by avoidance of preliminary chemical extractions and addi­ tions of reagents; (2) Sample volumes are small (1 to 50 /*1). The entire sample ...

Measurement of total and trimethyl lead in mammalian tissue is described, using ion exchange/high performance liquid chromatography in tandem with flameless atomic absorption spectrometry for lead-specific detection. All lead forms in whole blood and homogenates of soft tissue--brain, kidney, and liver--were liberated from tissue binding by treatment with dilute (3N) HCl for a period of 18 hr. ...

IN CONVENTIONAL atomic absorption spectrophotometry a solution of the sample is introduced into the flame as an aerosol by means of a nebulizer. However, commercial nebulizers are only about 5 efficient in forming fine droplets suitable for atomization by the flame ( I ) . Furthermore, a solution aspirated at a usual rate of 3-5 ml/min for about 10 sec produces a concentration signal extending ...

A primary atomization model for visco-elastic liquid is established based on the ligament formation assumption and dispersion relationships. Two linear instability analyses are used in presented paper. Both of them are involved in the primary atomization model and the calculated results are compared with published experimental data. After validation, the model is used to predict the effects of ...

Atomization spray of non-Newtonian liquid plays a pivotal role in various engineering applications, especially for the energy utilization. To operate spray systems efficiently and well understand the effects of liquid rheological properties on the whole spray process, a comprehensive model using Euler-Lagrangian approaches was established to simulate the evolution of the atomization spray for v...