Pure (S1) and Dy3+-doped α-Fe2O3 (S2 and S3) nanoparticles were prepared by a combustion synthesis method at 700 ºC for 8 h using Fe(acac)3 (Tris(acetylacetonato)Iron(III)) as raw material. Characterizations of the prepared powders were carried out by powder X-ray diffraction (PXRD). Structural analysis was performed b...

Pure (S1) and Dy3+-doped α-Fe2O3 (S2 and S3) nanoparticles were prepared by a combustion synthesis method at 700 ºC for 8 h using Fe(acac)3 (Tris(acetylacetonato)Iron(III)) as raw material. Characterizations of the prepared powders were carried out by powder X-ray diffraction (PXRD). Structural analysis was performed b...

To design a high-performance photocatalytic system with TiO2, it is necessary to reduce the bandgap and enhance the absorption efficiency. The reduction of the bandgap to the visible range was investigated with reference to the surface distortion of anatase TiO2 nanoparticles induced by varying Fe doping concentrations. Fe-doped TiO2 nanoparticles (Fe@TiO2) were synthesized by a hydrothermal me...

Using density functional theory (DFT) based electronic structure calculations, the effects of morphology of semiconducting nanostructures on the magnetic interaction between two magnetic dopant atoms as well as a possibility of tuning band gaps have been studied in the case of the bi-doped (ZnO)24 nanostructures with the impurity dopant atoms of the 3d late transition metals-Mn, Fe, Co, Ni, and...

Many recent studies have been reported on the photodegradation of the organic compounds in industrial wastewater in the presence of TiO2 semiconductor as photocatalyst. Heterogeneous photocatalysts using Iron as a dopant metal, so far, have been reported for various environmental applications. This paper highlights the recent advances and applications of Fe-TiO2 photocatalysis for the degradati...

In this work, a series of transition metal (Cr, Mn, Fe, and Co) doped kaolinite nanoclays were investigated by density functional theory (DFT) calculations. The influence of metal doping on geometric structure and electronic structure of kaolinite was analyzed. The ferromagnetic (FM), antiferromagnetic (AFM), and nonmagnetic (NM) states of transition metal (TM) doped kaolinite structures were s...

We studied the effect of dopants (Al, Ti, Zr) on the thermal stability of iron-nitride thin films prepared using a dc magnetron sputtering technique. Structure and magnetic characterization of deposited samples reveal that the thermal stability together with soft magnetic properties of iron-nitride thin films get significantly improved with doping. To understand the observed results, detailed F...

Ferroelectric Pb[Zr0.4Ti0.6]O3 ceramics codoped with La3+ and Fe3+ at dopant concentrations of 1.0 and 0.5 mol. %, respectively, were investigated by means of multifrequency electron paramagnetic resonance (EPR) spectroscopy. The results prove that iron is incorporated at the [Zr,Ti]-site, acts as an acceptor and favors the creation of charged (Fe′Zr,Ti − V •• O ) • defect dipoles that may give...

The magnetism of Fe and its alloys has been at the center of scientific and technological interest for decades. Along with the ferromagnetic nature of body-centered cubic Fe, the magnetic properties of face-centered cubic (fcc) Fe have attracted much attention. It is well known that fcc Fe is thermodynamically unstable at ambient conditions and not ferromagnetic. Contrary to what is known, we r...

The challenge of improving the efficiency of photo-electrochemical devices is often addressed through doping. However, this strategy could harm performance. Specifically, as demonstrated in a recent experiment, doping one of the most widely used materials for water splitting, iron (III) oxide (Fe₂O₃), with niobium (Nb) can still result in limited efficiency. In order to better understand the ha...