Ionic liquids (IL) and hyperbranched polymers (HyP) represent new classes of nonvolatile selective solvents. By measuring vapor-liquid equilibria (VLE) of azeotropic and close boiling systems in the presence of ionic liquids or hyperbranched polymers, separation factors are derived and the potential of using IL and HyP as entrainer for extractive distillation is discussed. Exemplarily, the supe...

−− The aim of this work is to simulate and analyze an extractive distillation process (extractive distillation and recovery columns) for the separation of Tetrahydrofuran (THF)-Water azeotropic mixture using Aspen Plus® and Aspen Split simulators. Calculation of vapor liquid equilibrium of Tetrahydrofuran–Water–Entrainer system was done using the NRTL model, which binary interaction parameters ...

In this contribution, a different pressure thermally coupled extractive distillation process has been applied on the separation of propylene and propane with aqueous acetonitrile (ACN) solution as entrainer. The novel distillation process integration is the combination of different pressure thermally coupled distillation (DPTCD) and extractive distillation (ED). Both the new process and the con...

The structure of the thermally coupled distillation systems offers some control challenges arising from the transfer of vapor (or liquid) streams between the columns. In particular, the presence of recycle streams for coupled schemes has influenced the notion that control problems might be expected during the operation of those systems with respect to the rather well-known behavior of conventio...

Batch distillation in a column with a middle vessel can avoid many of the disadvantages associated with the regular batch distillation processes. In this paper we present an experimental investigation of the separation of a zeotropic ternary mixture via total reflux operation and of the separation of an azeotropic binary mixture via batchwise extractive distillation. Moreover, the results obtai...

1,3-Butadiene, BD is produced from C4-cut by extractive distillation. The separation of 1,3-Butadiene from C4-cut is not possible through the conventional distillation processes, because several mixtures have consisted of close boiling points constituents and make azeotrope. The BASF extraction distillation process in BD unit of Jam and Amirkabir Petrochemical Company improves the relative vola...

Distillation separates compounds by the variation in how effortlessly they vaporize. The two main types of standard distillation comprise unremitting distillation and batch distillation. Unremitting distillation, as the name says, unremittingly takes a feed and separates it into two or more products. Batch distillation takes on lot (or batch) at a time of feed and splits it into products by sel...

The present work elaborates the process design methodology for the evaluation of the distillation systems based on the economic, exergetic and environmental point of view, the greenhouse gas (GHG) emissions. The methodology proposes the Heat Integrated Pressure Swing Distillation Sequence (HiPSDS) is economic and reduces the GHG emissions than the conventional Extractive Distillation Sequence (...