This paper reports on solvent-extraction studies of Ni(II) from sulfate solutions with LIX 84I (2-hydroxy-5-nonylacetophenoneoxime) as the extractant. The extraction of metal depends on the equilibrium pH of the aqueous phase and the extractant concentration. The transfer of metal follows a cation exchange-type mechanism: Ni2+ + 2HA --> NiA2 + 2H+. Extraction varies with the nature of the dilue...

The decontamination of dilute industrial effluents is a critical challenge for decreasing the environmental impact of mining and metallurgical activities. As an alternative to conventional processes, new extractant impregnated resins (EIRs) have been synthesized by the immobilization of Cyanex 301 and Cyanex 302 in alginate capsules using two different procedures (matrix-type immobilization vs....

Ionic liquids have many favorable properties over conventional diluents in solvent extraction. They provide an environmentally benign feature, adjustable polarity and, in some cases, higher extraction performances that remain however not predictable. As it may have a major role in extraction mechanisms, we evidence the supramolecular aggregation of HDEHP/TOPO extractant molecules in the [OMim][...

This is a communication on the removal of copper(II) ions from a residual mine water using an emulsified liquid membrane (ELM). The membrane was prepared by dissolving the extractant LIX-860 (a salicylaldoxime), used as a mobile carrier, and Span80, a surfactant, in kerosene. The ELM allowed an efficient metal transport from the feed solution towards the strip liquor, in experiments carried out...

The common use of soil-fertility control data in Croatia includes properties such as soil pH, organic matter content and plant-available phosphorus (P) and potassium (K) extracted by ammonium lactate (AL) solution. These data are commonly used for fertilizer recommendations for both field vegetable (Lončarić et al., 2003) and arable crops (Vukadinović et al., 1996). Also, the same soil data hav...

Viscum album L. is a hemiparasite and most often parasitic on deciduous trees, the chemical composition of semi-parasite plant can vary depending time harvest, type host tree. The object study was leaves mistletoe growing domestic apple tree, collected in vicinity city Stavropol, common pear, territory Belorechensky district Krasnodar Territory. aim comparative content phenolic compounds antiox...

In this study, extraction of amoxicillin (AMOX) ions from aqueous solution by liquid-liquid extraction (LLE) was investigated. The LLE process by response surface methodology (RSM) was carried out based on central composite design (CCD). The organic phase consisted of extractant and toluene as diluent. In this process, triethylamine (TEA), di-2-ethylhexyl phosphoric acid and mono-2-ethylhexyl p...

The oxidation-extraction desulfurization of Saudi Arabian crudes was conducted with hydrogen peroxide-acetic acid oxidation system. The selection of extractant, the optimization of oxidation-extraction conditions, and the exploration of desulfurization mechanism were studied. As DMF was used as the extractant, the optimal desulfurization rate of 35.11 % and oil recovery of 95 % were obtained at...

Monodisperse orthorhombic-phase BiF(3) nanocrystals with various shapes were prepared easily by a novel solvent extraction approach using an acid-base-coupled extractant. More importantly, the extractant used in this route can be recycled after synthesis. Our results show great promise for further extending the method to the preparation of other metal-fluoride nanoparticles.

A new soil extractant (HA) with the ability to extract NH4, NO3, and P from soil was developed and tested against 32 soils, which varied greatly in clay content, organic carbon (C), and soil pH. The extractant (HA) eliminates the need for separate phosphorus (P) extractants for acid and calcareous soils and maintains the extract pH, on average, within one unit of the soil pH. The extractant is ...