The synthesis and binding properties of new porphyrin cage compounds consisting of a rigid diphenylglycoluril part, which is connected via flexible bis(ethyleneoxy) spacers to a (metallo)porphyrin "roof", are reported. Binding of viologen guests and pyridine ligands in these porphyrin cages are accompanied by significant conformational reorganizations of the hosts. Despite these structural chan...

When depth of flow past a river bridge exceeds opening under the bridge, the flow under the bridge becomes pressurized. The water is directed downward and under the bridge deck, causing increase in velocity and shear stress on the bed thereby increasing bed scour. This is termed as Pressure Flow Scour. The present study investigates the phenomenon of pressure flow scour resulting from a submerg...

The effect of ligand structure on the magnetic resonance (MR) imaging and biodistribution of six gadolinium (Gd) chelates based on a hydroxypyridonate-terephthalimide (HOPO-TAM) ligand design was investigated. Modifications to the molecular structure of the Gd-HOPO-TAM chelates (hydrophilicity and aromatic group substitution) significantly influence the efficacy of imaging and biodistribution. ...

three unconventional details for plastic hinges of bridge columns subjected to seismic loads were developed, designed, and implemented in a large-scale, four-span reinforced concrete bridge. shape memory alloys (sma), special engineered cementitious composites (ecc), elastomeric pads embedded into columns, and post-tensioning were used in three different piers. the bridge model was subjected to...

Results are reviewed from a study on the distribution of surfactants in pressure-sensitive adhesive (PSA) films subsequent to the coating process. The PSAs are water-based acrylics synthesized with n-butyl acrylate, vinyl acetate and methacrylic acid and two commercially available surfactants, disodium (nonylphenoxypolyethoxy)ethyl sulfosuccinate (anionic) and nonylphenoxypoly(ethyleneoxy) etha...

general kind of encroachment of river is constructing a bridge on it. purpose of encroachment of river is occupation part of river and flood plain for constructing bridge. often being economical of bridge innovation affirmated that most of encroachment take place to river and flood plain, which this encroachment can be in form of embankment in flood plain of river or into the main bed of river ...