Herein, an ultrasound-assisted dispersive magnetic micro-solid phase extraction (DM-?SPE) approach, along with electrothermal atomic absorption spectrometry (ETAAS) for the determination of lead at trace level in spring, well, river mineral and tap water samples was developed. The step is based on synthesis PbS, following sonochemical decomposition L-cysteine used as sulphide precursor its anch...

A fast, simple, and reliable method for determination of hexavalent chromium species in soil aqueous and alkaline extracts has been developed. The procedure is based on the ion-pair extraction of Cr(VI) with methyltrioctylammonium chloride (Aliquat 336) into xylene. The extract is analyzed by flame (FAAS) or electrothermal atomic absorption spectrometry (ETAAS). The method allows the detection ...

The development of a sequential injection analysis manifold for the colorimetric determination of lead in water samples is described The concentration of lead was assessed from its catalytic effect on the reaction of resazurine reduction caused by sulfide in an alkali medium. To that effect, the reaction zone was stopped at the detector, and the time interval required for the attainment of an a...

a sensitive, selective and effective ionic liquid-based single drop microextraction technique was developed by using ionic liquid, 1-hexyl-3-methylimidazolium hexafluorophosphate, c6mimpf6, coupled with electrothermal atomic absorption spectrometry (etaas) for the determination of copper and silver in environmental samples. dithizone was used as chelating agent. several factors that influence t...

a combined electrodeposition-etaas technique has been applied to the analysis of pb, cd, co, ni, cr and mn in biological samples in order to overcome interferences and to minimize sample pretreatment. it requires minimal sample preparation with the electrolysis process aiding partial decomposition of the organic matrix, adequate for the release and deposition of trace elements. in an initial el...

The procedure for the reliable determination of Be in natural waters by ETAAS was elaborated. Various modifiers (EDTA, Ca(NO3)2, Mg(NO3)2, Pd(NO3)2 and the mixture of Pd(NO3)2 and Mg(NO3)2) for the determination of beryllium was examined. The applicability of the selected Mg(NO3)2 as the appropriate and generally used modifier for the determination of Be in the different types of natural waters...

Vortex-assisted surfactant-enhanced emulsification microextraction based on solidification of floating organic drop (VASEME-SFO) was used for preconcentration and speciation of antimony (ΙΙΙ, V) followed by electrothermal atomic absorption spectrometry (ETAAS). In this procedure, Triton X-114 was used as emulsifier and 1-undecanol was used as extraction solvent. This method is based on the comp...

Cellulose derivative resin (CDR) suspensions containing resin particles of cellulose nitrate (CDR(CN)), cellulose acetate (CDR(CA)), or cellulose triacetate (CDR(CTA)) were prepared as the sorbent for resin suspension injection (RSI) electrothermal atomic absorption spectrometry (ETAAS), in which fine resin particles holding a desired trace element were directly injected into the graphite tube ...

A combined electrodeposition-ETAAS technique has been applied to the analysis of Pb, Cd, Co, Ni, Cr and Mn in biological samples in order to overcome interferences and to minimize sample pretreatment. It requires minimal sample preparation with the electrolysis process aiding partial decomposition of the organic matrix, adequate for the release and deposition of trace elements. In an initia...