the phenylthiourea-substituted triethoxysilane as a silane agent was synthesized and grafted on highly ordered nanoporous silica (lus-1) with a textured morphology and hexagonal array. this material (tu-lus-1) contained 0.8 mmol/g of soft base phenylthiourea group and surface area 760 m2g-1 and was able to adsorb 0.75 mmolhg/g of tu-lus-1 in endothermic reaction.

Endotherms regulate their core body temperature by adjusting metabolic heat production and insulation. Endothermic body temperatures are therefore relatively stable compared to external temperatures. The thermal sensitivity of biochemical reaction rates is thought to have co-evolved with body temperature regulation so that optimal reaction rates occur at the regulated body temperature. However,...

In this paper, we explore the emergence and direct interaction of two different types of dissipative structure in a single system: self-replicating chemical spot patterns and buoyancyinduced convection rolls. A new Lattice Boltzmann Model is developed, capable of simulating fluid flow, heat transport, and thermal chemical reactions, all within a simple, efficient framework. We report on a first...

The steam−carbon reaction, which is the essential reaction of the gasification processes of carbon-based feed stocks (e.g., coal and biomass), produces synthesis gas (H2 + CO), a synthetically flexible, environmentally benign energy source. The reaction is very endothermic, which mandates high temperatures and a large expenditure of energy to drive the reaction. We have found that using microwa...

In this paper, the transformation process from Au8 to Au25 nanoclusters (NCs) is investigated with steady state fluorescence spectroscopy and time-resolved fluorescence spectroscopy at various reaction temperatures and solvent diffusivities. Results demonstrate that Au8 NCs, protected by bovine serum albumin, transform into Au25 NCs under controlled pH values through an endothermic reaction wit...

The hybrid CBS-QB3 electronic structure approach is used to calculate the reaction energetics for decomposition reactions of radicals formed from UV radiation of the polymer poly(methyl methacrylate) (PMMA). Relative to the photon created radical species, the decarboxylation reaction to form CO2 is exothermic whereas the reaction to form CO is endothermic. For degradation of the polymer in low-...

The phenylthiourea-substituted triethoxysilane as a silane agent was synthesized and grafted on highly ordered nanoporous silica (LUS- 1) with a textured morphology and hexagonal array. This material (Tu-LUS-1) contained 0.8 mmol/g of soft base phenylthiourea group and surface area 760 m2 g-1  and was able to adsorb 0.75 mmolHg/g of TU-LUS-1 in endothermic reaction.