In this paper, we demonstrate our ability to directly probe the molecular structures of the buried polymer/metal interface using sum frequency generation (SFG) vibrational spectroscopy. Spectroscopic data from different experimental approaches were compared and analyzed to deduce the molecular ordering information at a buried polymer/metal interface, i.e. the poly(n-butyl methylacrylate) (PBMA)...

Rhodamine B-tagged poly(alkyl cyanoacrylate) amphiphilic copolymers have been synthesised, characterised and successfully used to prepare fluorescent nanoparticles for human brain endothelial cell imaging, allowing their uptake and intracellular trafficking to be finely observed.

BACKGROUND Calyceal fistulas are common and difficult to treat after surgery of urinary collecting system. METHODS A 30-year old woman. The fifth day after receiving a cadaver donor renal allograft presented an acute rejection episode; fourteen days later presented an urinoma treated with a percutaneous drainage tube. Five days later surgical exploration was made, lower pole infarction and is...

uterine arteriovenous malformations (avms) are relatively rare disorders that can cause life-threatening vaginal bleeding. we describe three childbearing-age females, who had abdominal pain and heavy vaginal bleeding, and were diagnosed as uterine avm by color doppler and angiography. the patients received successful superselective transarterial embolization (tae) with n-butyl cyanoacrylate (nb...

Broadband dielectric measurements were carried out on di-n-butyl phthalate (DBP) under isothermal conditions at hydrostatic pressures up to 1.6 GPa. A comparison of the dielectric relaxation times with the viscosity revealed that no breakdown of the Einstein-Debye relation is induced by high compression. This absence of any decoupling is attributed to the weak intermolecular cooperativity of DB...

Newkome-type first, second and third generation dendrimers, having t-butyl (GB), ethyl (GE) and carboxylic (GA) end groups, were synthesized. A pyrene group, which can act as fluorescent sensor, was attached to the core of the dendrimers and their photophysical properties in aqueous solution were studied. These dendrimers were found to aggregate in aqueous solution, which manifested as an excim...

We report the synthesis of morphological uniform composites using miniemulsions of poly(tert-butyl acrylate) or poly(styrene) containing organically capped gold nanocrystals (NCs). The optical features of such hybrid structures are dominated by plasmonic effects and depend critically on the morphology of the resulting nanocomposite. In particular, we demonstrate the ability to tune the overall ...

We measured the form factor of bottle-brush macromolecules under good solvent conditions with small-angle neutron scattering and static light scattering. The systems under investigation are brushes, synthesized via the grafting-from route, built from a poly(alkyl methacrylate) backbone to which poly(n-butyl acrylate) side chains are densely grafted. The aim of our work is to study how the syste...

BACKGROUND Left ventricular free wall rupture (LVFWR) is a dramatic complication after myocardial infarction. We present our mid-term clinical and echocardiographic results of LVFWR with an epicardial patch without cardiopulmonary bypass. METHODS From February 1993 to May 2001, 17 patients underwent surgery for LVFWR. The mean age+/-SD of 12 males and 5 females was 68+/-10 years. All patients...