The rotational barrier about the C S bond in fluorocarbonylsulfenyl chloride [FC(0)SC1] is investigated using the C N D O method. The results confirm the existence of planar eis and trans conformers and the higher stability of the latter, as suggested by previous vibrational results. The valence force constants in FC(0)SC1 were also calculated and the values obtained compare favourably with res...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

We determine theoretically the relation between the total number of protons Np and the mass number A (the charge to mass ratio) of nuclei and neutron cores with the model recently proposed by Ruffini et al. (2007) and we compare it with other Np versus A relations: the empirical one, related to the Periodic Table, and the semi-empirical relation, obtained by minimizing the Weizsäcker mass formu...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

The issue of using remotely sensed surface temperature to estimate the area-average sensible heat flux over surfaces made up of different vegetated patches has been investigated. The performance of three aggregation procedures, ranging from physically based through semi-empirical, to entirely empirical has been assessed by comparing measured and simulated area-average sensible heat flux. The re...

abstract from longley, the various equations for determining the runoff to water management are presented by the researchers that are widely used in hydrologic sciences. in this study by using observational data, was evaluated empirical, artificial neural network (ann) and ca-active neuro-fuzzy inference system (canfis) models in estimation of runoff. for this purpose, by using climatic and phy...

runoff estimation resulted from precipitation is the basis of more study in various develop and exploit design from water resource, then its measure and calculation due to environmental bottlenecks, always have a plenty problem. as a result of the importance of output runoff estimation and flood volume in watershed for the sake of country integrated watershed management in this study tried to 9...

We consider large scale empirical risk minimization (ERM) problems, where both the problem dimension and variable size is large. In these cases, most second order methods are infeasible due to the high cost in both computing the Hessian over all samples and computing its inverse in high dimensions. In this paper, we propose a novel adaptive sample size second-order method, which reduces the cos...

this paper gives an overview of the difficulties associated with the design of hard rock pillars in south african mines. recent examples of large scale pillar collapses in south africa suggest that these were caused by weak partings which traversed the pillars. currently two different methods are used to determine the strength of pillars, namely, empirical equations derived from back analyses o...