A new method for the positive identification of elemental sulfur in explosives and explosive residues is developed. Following a carbon disulfide wash of explosives or explosive residues, a sample of the extracted material is injected onto a gas chromatography (GC) column, then analyzed via mass-selective (MS) detection. A positive identification of elemental sulfur is based on both retention ti...

Sulfur forms deposited on carbonaceous surfaces after exposure to hydrogen sulfide were analyzed using XPS and XANES. Higher temperatures promote the formation of organic sulfur and the presence of H2S during the cooling process increased elemental sulfur content. Temperatures between 400–600 C were found to be optimal for producing effective mercury uptake sorbents. The increased amount of sul...

Lambs fed semipurified diets supplemented with DL-methionine, hydroxy analog of methionine, calcium sulfate, sodium sulfate or elemental sulfur gained faster, consumed more dry matter, and digested and retained greater weights of nitrogen and sulfur (P<.01) than lambs fed a sulfur deficient diet. Lambs fed a sulfur deficient diet had severe weight losses in 40 days and were removed from the exp...

Sulfur compounds in intermediate valence states, for example elemental sulfur, thiosulfate, and tetrathionate, are important players in the biogeochemical sulfur cycle. However, key understanding about the pathways of oxidation involving mixed-valance state sulfur species is still missing. Here we report the sulfur and oxygen isotope fractionation effects during the oxidation of tetrathionate (...

Sour gas wells frequently co-produce elemental sulfur which can cause catastrophic corrosion of mild steel. As producing wells become increasingly sour, the incidence of sulfur corrosion will likely increase. Despite the severity of this problem, limited mechanistic information about this process exists in the literature. The objective of this study is investigation of the corrosion mechanism i...

BACKGROUND Acidithiobacillus caldus (A. caldus) is widely used in bio-leaching. It gains energy and electrons from oxidation of elemental sulfur and reduced inorganic sulfur compounds (RISCs) for carbon dioxide fixation and growth. Genomic analyses suggest that its sulfur oxidation system involves a truncated sulfur oxidation (Sox) system (omitting SoxCD), non-Sox sulfur oxidation system simila...

A covalent triazine framework (CTF) with embedded polymeric sulfur and a high sulfur content of 62 wt % was synthesized under catalyst- and solvent-free reaction conditions from 1,4-dicyanobenzene and elemental sulfur. Our synthetic approach introduces a new way of preparing CTFs under environmentally benign conditions by the direct utilization of elemental sulfur. The homogeneous sulfur distri...

The reaction of pyridyl-1-azaallyl germanium(ii) chloride RGeCl () [R = {N(SiMe(3))C(Ph)C(SiMe(3))(C(5)H(4)N-2)}] with lithium metal afforded the dimeric germanium(i) compound [(RGe)(2)] (); compound reacts with an excess of elemental sulfur to afford the novel germanium analogue of a dithiocarboxylic acid anhydride [{Ge(S)R}(2)S] () via the insertion of elemental sulfur into the Ge(i)-Ge(i) bo...

Elemental sulfur (S8) is often present in considerable amounts in sour gas reservoirs at the reservoir conditions (pressure and temperature). For the isothermal conditions in the reservoir, the reduction in reservoir pressure below a critical value will cause the elemental sulfur to deposit in the formation. Sulfur deposition can cause severe loss in the pore space available for gas, and in tur...

BACKGROUND Elemental sulfur, "the oldest of all pesticides," is the most heavily used agricultural pesticide in California and Europe. Sulfur is considered relatively safe and is used in both conventional and organic farming systems. Adverse respiratory effects have been reported in applicators and animals, but the effect on residential populations, and especially on children living in proximit...