investigation of the redox properties of drugs and their determination are performed by electrochemical techniques. data obtained from electrochemical techniques are often correlated with molecular structure and pharmacological activity of drugs. in this regard, different modified electrodes were applied as sensors for quantification of different drugs.a nanocomposite of reduced graphene oxide-...

In several recent publications 1-6 we have shown experimentally that the acidic groups present in collodion are the primary cause of its electrochemical activity in solutions of strong inorganic electrolytes. The surface concentration of these acidic dissociable groups is assumed to determine the degree of electrochemical activity of any given collodion sample. The abundance of these groups var...

in this study ptfeco ternary alloys nanoparticles of three dimentional (3d) rhombus shapes dispersed on graphene nanosheets (ptfeco/gr) were successfully prepared and studied as electrocatalysts for oxygen reduction reaction (orr) in polymer-electrolyte fuel cells. a combination of analytical techniques including powder x-ray diffraction, x-ray photoelectron spectra, inductively coupled plasma-...

1. Theoretical considerations lead to the conclusion that dissociable acidic groups present to a varying extent in different collodion preparations determine the electrochemical behavior of membranes cast from these preparations. It is further reasoned that the base exchange capacity of the collodion surfaces is the true quantitative measure of the abundance of the dissociable groups. 2. The co...

In this study PtFeCo ternary alloys nanoparticles of three dimentional (3D) rhombus shapes dispersed on graphene nanosheets (PtFeCo/Gr) were successfully prepared and studied as electrocatalysts for oxygen reduction reaction (ORR) in polymer-electrolyte fuel cells. A combination of analytical techniques including powder X-ray diffraction, X-ray photoelectron spectra, inductively coupled plasma-...

A recently constructed polyglycine modified carbon paste electrode (PGMCPE) was employed to evaluate the electrochemical behavior of methyl orange (MO). The developed electrode was characterized by FESEM to understand the morphology of the modified electrode and bare carbon paste electrode (BCPE). The modified electrode exhibits an excellent electrochemical activity towards the oxidation of MO....

potentiometric investigation on {h2o+nano3+peg1500} mixtures were made at t=308.15k, using electrochemical cells with two ion-selective electrodes, (na+ glass) as the cation ion-selective electrode against (no3- solvent-polymer pvc) as the anion ion-selective electrode. the mean ionic activity coefficients of nano3 were measured at different concentrations of  nano3 and peg. maximum concentrati...

A strong relationship between the surface structure and the redox activity of Li2O2 is visualized directly using scanning electrochemical cell microscopy, employing a dual-barrel nanopipette containing a unique gel polymer electrolyte. These measurements reveal considerable local heterogeneity with significantly enhanced electrochemical activity at toroidal Li2O2 structures when compared to the...

Investigation of the redox properties of drugs and their determination are performed by electrochemical techniques. Data obtained from electrochemical techniques are often correlated with molecular structure and pharmacological activity of drugs. In this regard, different modified electrodes were applied as sensors for quantification of different drugs.A nanocomposite of reduced graphene oxide-...