In the framework of fundamentals of smart materials and structures, a proper mathematical modeling of electro-kinetic transport phenomena in micro-structures adhering to the law of conservation of mass is suggested. The reference multiphase medium is described by a nonlinear Poisson–Nernst–Planck model stated in a heterogeneous pore-particle space disjoint by the interface. For physical consist...

Electro-kinetic fluids can be modeled by hydrodynamic systems describing the coupling between fluids and electric charges. The system consists of a momentum equation together with transport equations of charges. In the dynamics, the special coupling between the Lorentz force in the velocity equation and the material transport in the charge equation gives an energy dissipation law. In stationary...

in the present work, the modified nickel electrode was electrochemically fabricated and tested for the electro-oxidation of paracetamol in alkaline media. the methods of cyclic voltammetry (cv), chronoamperometry (ca), and impedance spectroscopy (eis) were used to determine kinetic parameters such as transfer coefficient (α), the catalytic reaction rate constants (k), and the diffusion coeffici...

Electro-osmosis is the flow produced by the action of an electric field on a fluid with a net charge, which is created by the Zeta potential and confined in the Debye layer. This basic phenomenon in the electro-kinetic transport plays an important role in the microfluidic systems being explored today because it can be applied to a variety of MEMS devices. This paper presents global and point-wi...

Nonlinear electro-osmotic behaviour of dilute non-adsorbing polymer solutions with low salinity is investigated using Brownian dynamics simulations and a kinetic theory. In the Brownian simulations, the hydrodynamic interaction between the polymers and a no-slip wall is considered using the Rotne-Prager approximation of the Blake tensor. In a plug flow under a sufficiently strong applied electr...

The solution phase transport and direct electrode kinetics of electro-enzymes are described in terms of a simple model in which the steady state reaction/diffusion equation for enzyme is solved subject to physically realistic boundary conditions. Two physically realizable situations are described: the semi infinite and the membrane bounded case. Limiting expressions for the reaction flux are de...

In the present work, the modified nickel electrode was electrochemically fabricated and tested for the electro-oxidation of paracetamol in alkaline media. The methods of cyclic voltammetry (CV), chronoamperometry (CA), and impedance spectroscopy (EIS) were used to determine kinetic parameters such as transfer coefficient (α), the catalytic reaction rate constants (k), and the diffusion coeffici...

Now a days the Consumption of power has been increased tremendously. In order to meet the demand of Power by various units various setups has been introduced for effective power generation. In this Project electrical power is being generated as non-conventional method by simply passing vehicles on to the specially designed Roller Setup. This method of Electrical power generation needs no input ...