Inevitable presence of pesticides in foods demands development of efficient multiresidue methods for risk evaluation. Extraction of pesticide trace contaminants from foodstuffs is a laborious task. Development of reliable sample preparation procedures, characterized by the simplicity of both the operations and the devices involved in analytical process is need of the hour. Effective minimizatio...

in this study, a sensitive method of dispersive liquid phase microextraction based on ion-pair combined with the flame atomic absorption spectrometry was proposed for the determination of trace ni(ii) using aliquat 336-chloride as ion pair agent. several factors which have effect on  the microextraction efficiency of ni(ii), such as ph, extraction and dispersive solvent type and their volume, c...

In this study, an analytical methodology based on a combination of dispersive liquid–liquid microextraction with laser-induced breakdown spectrometry was evaluated for simultaneous pre-concentration, speciation and detection of Cr. The microextraction procedure was based on the injection of appropriated quantities of 1-undecanol and ethanol into a sample solution containing the complexes formed...

Solvent extraction remains one of the fundamental sample preparation techniques in the analysis of environmental solid samples, but organic solvents are toxic and environmentally harmful, therefore one of the possible greening directions is its miniaturization. The present review covers the relevant research from the field of application of microextraction to the sample preparation of environme...

A sensitive determination method was developed for the analysis of pyrethroid pesticide residues in tomato samples using ionic liquid-based dispersive liquid-liquid microextraction. A hydrophobic ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) and acetonitrile were used as the extraction solvent and dispersive solvent, respectively. The following experimental parameters affecting...

A new dispersive liquid–liquid microextraction separation/preconcentration procedure as a rapid sample-preparation technique is proposed for detection of ultra trace amounts of Au(III) in various media by flame atomic absorption spectrometry using 1,5-diphenyl-1,3,5-pentanetrione as chelating agent. Carbon tetrachloride and methanol were used as extraction and dispersive solvents, respectively....

In this work, two approaches based on Dispersive Liquid-Liquid MicroExtraction (DLLME) and Dispersive Liquid-Liquid MicroExtraction based on Solidification of Floating Organic Drop (DLLME-SFO) were compared for the extraction and preconcentration of crocin from saffron and biological samples. Different DLLME and DLLME-SFO parameters influencing the extraction efficiency were studied and opt...

background: a new microextraction method named dispersive liquid-liquid microextraction (dllme) for determination of chloroform in pool water and blood of swimmers after swimming is described. methods: this method was performed based on coupling dispersive liquid-liquid microextraction (dllme) with gas chromatog­raphy-mass spectrometry (gc-ms). methanol and trichloroethylenes were used as the d...

abstract polycyclic aromatic hydrocarbons (pahs) are classified as persistent and carcinogenic organic pollutants. pahs contamination has been reported in water. many of relevant regulatory bodies such as eu and epa have regulated the limit levels for pahs in drinking water. in this study, 13 priority polycyclic aromatic hydrocarbons (pahs) were determined in tap water samples of tehran and wat...