Recent developments in separation enhanced reaction processes using membranes and adsorbents, highlighted here, have proven their potential for carbon dioxide conversion to methanol dimethyl ether.

A synthesis of ±-cherylline dimethyl ether is reported. The key steps involved are Michael-type addition, radical azidonation of an aldehyde, Curtius rearrangement, and reduction of an isocyanate intermediate followed by Pictet-Spengler cyclization.

3.1 PRODUCTION OF CLEAN SYNTHESIS GAS......................................................................... 9 3.1.1 Biomass Gasification .............................................................................................. 9 3.1.2 Gas Cleanup.......................................................................................................... 10 3.2 CONVERSION OF SYNTHESIS GAS T...

This work includes a modelling and simulation of dimethyl ether direct synthesis in a tubular type reactor with hybrid catalysts bed. The results of simulation show that the loading ratio of methanol synthesis and dehydration catalysts has a important influence on product yield.

hydrogen was produced by steam reforming of dimethyl ether (dme) using a physical mixture of commercial hzsm-5 zeolite (for dme hydrolyzing) and cu/zno/al2o3 (for methanol steam reforming) as a catalyst in a fixed bed reactor. the experiments were performed at atmospheric pressure and in a temperature range from 270 to 310 °c. the effects of feed temperature and gas hourly space velocity (ghsv)...

Ab&raet-Enantioselective syntheses of a-alkenyl glycines of type 10 and of type 23 are described that provide these uncommon ammo acids with predictable conf&uration and with ec-values of ~~95%. Both approaches are based on the bislactim ether method developed by SchBllkopf et al. As for 10: The lithiated his-lactim ether 6 of cyclo(t-val-gly) is reacted with 2_i(dimethyl t-butyl)silyl]alkanals...

The synthesis and application of dimethyl carbonate (DMC) are achieving increasing importance due to its low toxicity and versatile reactivity. DMC can be used as environmentfriendly intermediate and starting material for organic synthesis via carbonylation and it can replace methylating agents such as dimethyl sulphate and methyl halides [1–3]. DMC is also being considered as a component for r...

h-zsm-5 nano-zeolites were synthesized by hydrothermal method using tetrapropylammonium hydroxide (tpaoh) as a template in the presence of various tpabr concentrations. the effect of different tpabr/tpaoh molar ratios was studied on the catalytic performance of dehydration of methanol to dimethyl ether (dme) in a fixed bed reactor under the same operating conditions (t=300°c, p=1 atm, and whsv=...