The internal defects and shape of cyclotrimethylenetrinitramine (RDX) crystal are critical parameters for the preparation of reduced sensitivity RDX (RS-RDX). In the current study, RDX was re-crystallized and spheroidized to form the high-quality RDX that was further characterized by purity, apparent density, size distribution, specific surface area, impact sensitivity, and shock sensitivity. T...

The feasibility of exploiting plasma chemistry to study the chemical reactions between metallic nanoparticles and molecular explosives such as cyclotrimethylenetrinitramine (RDX) has been demonstrated. This method, based on laser-induced breakdown spectroscopy, involves the production of nanoparticles in a laser-induced plasma and the simultaneous observation of time-resolved atomic and molecul...

The Ultra-nanocrystalline diamond (UNCD) was synthesized by the detonation of a high explosive mixture in water confinement. The presence of a diamond phase was revealed by X-ray diffraction (XRD) and transmission electron microscopy (TEM). X-ray line broadening (XRLB) was used to evaluate the peak profiles of diamond nanoparticles and their corresponding average crystallite sizes. The micro st...

Constitutive relationships in the crystalline energetic material -cyclotrimethylenetrinitramine -RDX have been investigated using first-principles density functional theory. The equilibrium properties of -RDX including unit cell parameters and bulk modulus, as well as the hydrostatic equation of state EOS , have been obtained and compared with available experimental data. The isotropic EOS has ...

The performance of density functional theories (DFT) in predicting structural parameters for six conventional energetic materials (EM) over various degrees of compression was examined for a wide range of pressures. The systems studied were nitromethane, 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX), cyclotrimethylenetrinitramine (RDX), 2,4,6,8,10,12hexanitrohexaazaisowurzitane (CL-20), 2...

Graphene oxide (GO)-based nanocomposites are promising additives for practical applications of cyclotrimethylenetrinitramine (RDX). GO is not only an excellent support nanoparticles, but also has independent catalytic activities, which have been well understood. In this study, the reactive molecular dynamics simulation method employed to investigate kinetics and fundamental mechanisms thermal d...

Solid-state geometry optimizations and corresponding normal-mode analysis of the widely used energetic material cyclotrimethylenetrinitramine (RDX) were performed using density functional theory with both the generalized gradient approximation (BLYP and BP functionals) and the local density approximation (PWC and VWN functionals). The structural results were found to be in good agreement with e...

The sensing and differentiation of explosive molecules is key for both security and environmental monitoring. Single fluorophores are a widely used tool for explosives detection, but a fluorescent array is a more powerful tool for detecting and differentiating such molecules. By combining array elements into a single multichannel platform, faster results can be obtained from smaller amounts of ...