copper complexes of [cu(phen)(tda)].2h2o(1) and [(phen)2cu(µ-tda) cu(phen)](clo4)2.1.5h2o (2) (where phen is 1,10-phenanthroline and tda2- is thiodiacetate) have been synthesized. both complexes were characterized by elemental analysis, ir, uv–vis spectroscopy and cyclic voltammetry. their solid state structures were determined by the single crystal x-ray diffraction method. complex 1 is mononu...

The copper(II) complex [Cu(pic)2]·2H2O was synthesized with 2-picolinic acid (Hpic) and copper acetate as reactants by room temperature solid-solid reaction. The composition and structure of the complex was characterized by elemental analyses, single crystal X-ray diffraction, X-ray powder diffraction, FT-IR spectroscopy and thermogravimetry-differential scanning calor...

the oxidative modification of low density lipoprotein (ldl) may play an important role in atherogenesis. antioxidants that can prevent ldl oxidation may act as antiatherogens. our understanding of the mechanism of ldl oxidation and factors that determine its susceptibility to oxidation is still incomplete. copper is a candidate for oxidizing ldl in atherosclerotic lesions. the binding of copper...

a simple and sensitive extraction-fluorimetric method for the determination of copper is reported. the 1,7-diaza-15-crown-5-copper-rose bengal (da15c5-cu-rb) ternary complex is quantitatively extracted into chloroform, diluted with ammoniacal acetone and its fluorescence intensity is measured at 570 nm with excitation at 540 nm. a linear calibration graph was obtained over the copper concentrat...

The oxidative modification of low density lipoprotein (LDL) may play an important role in atherogenesis. Antioxidants that can prevent LDL oxidation may act as antiatherogens. Our understanding of the mechanism of LDL oxidation and factors that determine its susceptibility to oxidation is still incomplete. Copper is a candidate for oxidizing LDL in atherosclerotic lesions. The binding of copper...

A novel ternary Schiff base ligand (HL) of ONO type and its copper (II) complex weresynthesised using 2-aminophenol and o-acetoacetotoluidide. They have been characterised by theusual analytical and spectral methods. The interaction of the complex with calf-thymus (CT)DNA has been investigated by UV-Vis, viscosity measurement, cyclic voltammetry anddifferential pulse voltammetry studies. The re...

The oxidative modification of low density lipoprotein (LDL) may play an important role in atherogenesis. Antioxidants that can prevent LDL oxidation may act as antiatherogens. Our understanding of the mechanism of LDL oxidation and factors that determine its susceptibility to oxidation is still incomplete. Copper is a candidate for oxidizing LDL in atherosclerotic lesions. The binding of copper...

Copper(II)  complex  [Cu(dmbt)2(H2O)](ClO4)2 (1)  was  prepared  from  the  reaction  of  copper(II) perchlorate  hexahydrate  with  2,2'-dimethyl-4,4'-bithiazole  (dmbt)  ligand  in  methanol  at  ambient temperature. The complex was quantitatively and qualitatively characterized by elemental analysis, absorption  and  infrared  spectrometries.  Complex  [Cu(DMSO)5](ClO4)2 (2)  was  also  synt...

a new method for the determination of trace copper(ii) in food samples by cloud point extraction(cpe) combined with flame atomic absorption spectrometry(faas) is presented and evaluated. the method is based on the fact that hydrophobic complex of copper(ii) with sodium diethyldithiocarbamate (ddtc) was formed at ph 6.0 and subsequently the hydrophobic complex was extracted into surfactant-rich ...