Copper(II)  complex  [Cu(dmbt)2(H2O)](ClO4)2 (1)  was  prepared  from  the  reaction  of  copper(II) perchlorate  hexahydrate  with  2,2'-dimethyl-4,4'-bithiazole  (dmbt)  ligand  in  methanol  at  ambient temperature. The complex was quantitatively and qualitatively characterized by elemental analysis, absorption  and  infrared  spectrometries.  Complex  [Cu(DMSO)5](ClO4)2 (2)  was  also  synt...

in this research project, the nitrito nitro isomerization of [co (nh3)5no2]f2 complex has been studied. isomerization of this complex in the solid state follows a first order kinetics. the rate of isomerization at different temperatures was determined using a fourier transform lnfrared spectrophotometer. ? and ? are calculated at 298 k. the infrared, visible and ultraviolet spectra of this comp...

due to the antitumor activity of gallium mal complex, as well as recent findings on new targeted biomolecules in malignant cells through this complex, the development of radiolabeled gallium complex for future imaging studies was targeted. ga-67 labeled 3-hydroxy-2-methyl-4h-pyran-4-onate (ga-67 mal) was prepared using freshly prepared ga-67 chloride and 3-hydroxy-2-methyl-4h-pyran-4-onate in a...

introduction: due to the interesting pharmacological properties of radiolabeled metal oxine derivatives such as cell internalization, tumor avidity and antiproteosome activity, 111in-tris[8-hydroxy-2-methylquinoline] (111in-hmq) was developed in this study. methods: 111in-hmq was prepared using 111incl3 and 8-hydroxy-2-methylquinoline (hmq) for 60 min at 100°c (radiochemical purity: >99% itlc, ...