Nickel nanoparticles (Ni NPs) are quite interesting because they exhibit high catalytic activity, high selectivity and high efficiency in fuel cells [1, 2]. However the coke-formation takes place in these NPs involving chemical reactions. For instance the CO2 reforming of methane gas in the presence of Ni NPs leads to the formation of coke containing predominantly the carbon nanotubes (CNTs) [3...

Lignin is the most difficult to be converted and most easy coking component in biomass catalytic pyrolysis to high-value liquid fuels and chemicals. Catalytic conversion of guaiacol as a lignin model compound was conducted in a fixed-bed reactor over ZSM-5 to investigate its conversion and coking behaviors. The effects of temperature, weight hourly space velocity (WHSV) and partial pressure on ...

Coke strength is the most important characteristic for retaining permeability in the bed of a blast furnace. In the present study, coke was coated with phenolic resin in order to improve the coke strength, and a nanoindentation method was used to estimate the strength of the coated coke after reaction under CO2 atmosphere. The elastic modulus was measured for the microporous coke substrate,. Th...

SHAHAB is a PC- based simulator developed by Olefin Research Group (ORG), with the simultaneous simulation of the reactor, the firebox, the convection section and the transfer line exchanger in steam Cracking units. The reaction mechanism of thermal cracking of hydrocarbons is generally accepted as free-radical chain reactions. Using a rigorous kinetic model, a complete reaction network for rep...

PURPOSE Despite the presence or absence of artificial sweeteners in cola drinks, both regular and diet soft drinks still contain phosphoric and citric acid, which contributes to the total acidic challenge potential on enamel. The purpose of this study was to assess the plaque pH, in vivo, after a substrate challenge of diet and regular soft drinks. METHODS Seventeen subjects were recruited fo...

Syrian petroleum coke, produced by a delayed coking unit, is characterized by a high percentage of fines which tends to reduce its commercial value. Blending coke fines using appropriate binders, such as bitumen and polyacrylic acid, can lead, however, to an improved coke that is similar in structure, appearance and other properties to better-quality coke lumps. In this work, samples of Syrian ...

Production of iron through BF route is still a dominant route and coke is a major raw material and energy source for the blast furnaces. The process of coal carbonization in slot ovens is one of the major sources of atmospheric pollution in an Integrated Steel Plant. Coke making process involves coal preparation, carbonization and coke handling operations. To meet the demand of Blast Furnaces o...

Calcined coke is a competitive material for making carbon anodes for smelting of alumina to aluminum. Calcining is an energy intensive industry and a significant amount of heat is exhausted in the calcining process. Efficiently managing this energy resource is tied to the profit margin and survivability of a calcining plant. To help improve the energy efficiency and reduce natural gas consumpti...

The calcined petroleum cokes are used in production of aluminum anode-grade, graphite electrode, needle-grade, titanium dioxide pigments. Petroleum coke (green and calcined) is produced by the high pressure thermal decomposition of heavy petroleum process streams and residues. Green coke undergoes additional thermal processing to produce calcined coke. Various properties of calcined cokes from ...

The objective of this work was to analyze the activity of petroleum coke and of activated carbons prepared from this material in the ozonation of aromatic contaminants of low biodegradability. 1,3,6-Naphthalenetrisulphonic acid (NTS) was selected as model compound for the study. The presence of the original coke during 1,3,6-naphthalenetrisulphonic acid ozonation produced a slight increase in t...