نتایج جستجو برای: co oligomerization of olefins

تعداد نتایج: 21196680  

2005
Hongjun Zhu Mei Wang Chengbing Ma Bo Li Changneng Chen Licheng Sun

A series of salen-type zirconium complexes of the general formula LZrCl2 (L = N,N 0-ethylenebis(salicylideneiminate), 3a; N, N 0-ethylenebis(3,5-di-tert-butylsalicylideneiminate), 3b; N,N 0-ethylenebis(5-methoxysalicylideneiminate), 3c; N,N 0-ethylenebis(5chlorosalicylideneiminate), 3d; N,N 0-ethylenebis(5-nitrosalicylideneiminate), 3e; N,N 0-o-phenylenebis(salicylideneiminate), 4a; N,N 0-o-phe...

2014
Marzena BIAŁEK Wioletta OCHĘDZAN-SIODŁAK Katarzyna DZIUBEK Krystyna CZAJA

Introduction Middle 1950s may be treated as the beginning of the age of plastics – their global production in last 60 years have increased from approx. 1.5 mln to almost 290 mln tons. The dominating position in production and consumption of these materials for many years has been occupied by polyolefins (in Europe 48% from 57 mln tons of plastics) [1]. Forecasters predict that in coming years t...

Journal: :Chemical communications 2012
Chungsik Kim Tatsuya Uchida Tsutomu Katsuki

Highly enantioselective and good to high-yielding aziridination of conjugated and non-conjugated terminal olefins and cyclic olefins was achieved using a newly designed Ru(CO)(salen) complex as the catalyst in the presence of SESN(3) under mild conditions.

Journal: :Organometallics 2012
Loi H Do Jay A Labinger John E Bercaw

To explore the possibility of producing a narrow distribution of mid- to long-chain hydrocarbons from ethylene as a chemical feedstock, co-oligomerization of ethylene and linear α-olefins (LAOs) was investigated, using a previously reported chromium complex, [CrCl(3)(PNP(OMe))] (1, where PNP(OMe) = N,N-bis(bis(o-methoxyphenyl)phosphino)methylamine). Activation of 1 by treatment with modified me...

Journal: :Journal of the American Chemical Society 2013
Marinus A Bigi M Christina White

Development of a mild (35 °C, no Brønsted acids) tandem Wacker oxidation-dehydrogenation of terminal olefins was accomplished using palladium(II) and hypervalent iodine co-catalysis. The reaction affords linear aryl and alkyl α,β-unsaturated ketones directly from readily available terminal olefins in good yields (average 75% per step) with excellent functional group tolerance and chemo- and ste...

The SiO2 supported cobalt-iron nano catalysts were prepared by the sol-gel method. This research investigated the effects of (Co/Fe) wt.%, different Co/Fe ratio at different temperature and loading of KCl wt.% for Fisher-Tropsch synthesis (FTS). The results were showed that the catalyst containing 50 wt.% (Co/Fe)/SiO2 (Co/Fe ratio is 70/30) which promoted with 0.6 wt.% KCl is an optimal nano ca...

Journal: :Dalton transactions 2010
Laura L Lazarus Richard L Brutchey

We report on the activity of fullerene-supported OsO(4) catalysts in the achiral dihydroxylation of olefins using N-methylmorpholine N-oxide as co-oxidant. The fullerene-supported OsO(4) catalysts can selectively dihydroxylate olefins with conversions up to 95% after 48 h without leaching, and the catalysts can be recovered and recycled several times.

2002

Superoxide Dismutase-Based Third-Generation Biosensor for Superoxide Anion Electrochemical Immunoassay Moving into the Fast Lane Characterization and Reactions of Previously Elusive 17Electron Cations: Electrochemical Oxidations of (C H )Cr(CO) and (C H )Co(CO) in the Presence of [B(C F ) ] Although chemical redox reagents can be highly selective, many produce toxic b y p r o d u c t s . I n c ...

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