A series of novel pyrazoline derivatives 5-(substituted aryl)-3-(3,4-dimethoxyphenyl)-1-(2,4dinitrophenyl)-4,5-dihydro-1H-pyrazole (5a-l) were synthesized by heating 2,4-dinitrophenyl hydrazine (4) with (E)-3-(3,4-dimethoxyphenyl)-1-substituted aryl prop-2-en-1-one (3) in presence of catalytic amount of concentrated H2SO4. The structures of the novel derivatives were confirmed by various spectr...

A series of tris (α-naphthyl) bismuth (V) carboxylates (α-C10H7)3Bi(OCOR)2 where OCOR = p-trifluoromethyl mandelate, pmethoxy mandelate, salicylate, 2pyrazine carboxylate, mandelate have been synthesised and characterised by solid state infrared, H and C NMR spectroscopy, molecular weight and conductance measurements. The newly synthesized derivatives are monomeric in benzene and non ionic in a...

The recent revival of the study organic natural products as renewable sources medicinal drugs, cosmetics, dyes, and materials motivated creation general purpose structural databases. Dereplication, efficient identification already reported compounds, relies on grouping structural, taxonomic spectroscopic databases that focus a particular taxon (species, genus, family, order, etc.). A set freely...

Diesel fuels of 50 and 15 ppm of sulfur content were produced in a pilot plant by upgrading light catalytic cracking gas oil (LCO) during 10 weeks of continuous operation. The end-of-run catalysts were characterized before and after soluble coke extraction by CH2Cl2. The cokes were characterized by CNMR, TPO, GC-MS, and elemental analysis. Catalyst surfaces were characterized by XPS, CO adsorpt...

coumarins are bioactive secondary metabolites and could be found in the fruits of umbelliferae. prangos asperula boiss. is an iranian native plant which is found wild in many regions of iran. osthol, a prenylated coumarin, was isolated from the hexane extract of the fruits of p. asperula and its structure was elucidated using 1 hnmr, 13 cnmr, ir and ms spectra. the essential oil of the aerial p...

Isolation and identification of secondary metabolite compound from chloroform fraction of Usnea longissima and its bioactivity test as an antibacterial had been conducted. The isolation of the chemical compound was performed by using Gravity Column Chromatography (GCC) and ThinLayered Chromatography (TLC). The result showed the needle crystal shaped isolated compound with translucent white colo...

Modification of chitosan biopolymer was achieved by grafting (3-phenyl-1H-pyrazole-4-carbaldehyde) by the Schiff base reaction to synthesize a new chitosan derivative (ChD). The formation of the product was confirmed by FTIR, XRD and CNMR analysis. The grafted molecule provided additional nitrogen bearing groups as binding sites. The new derivative was used to investigate the removal of Cr (VI)...