Interactions between Cd, pillared clays and chalcogenedies have been studied using nanomineralogical experiments. XRD, DSC and chemical analysis. The synchrotron-based X-ray absorption spectroscopy (XAS) was applied to characterize the reaction phases. The mean bond lengths between, Cd-S, Fe-S, Sb-S, Cd-Cd (in chalcogenedies), Al-Cd, Cd-Ti, and Fe-Cd, (in pillared clays) were determined by XAS ...

In this work, three types of natural clays including kaolinite, montmorillonite, and illite with different molecular structures, as adsorbents, are selected for the removal of methylene blue dye, and their performance is investigated. Also the optimization and the analysis of the dye adsorption mechanism are performed using the response surface methodology, molecular modeling, and experimental ...

Examination of clays from surface and basal horizons of four Scottish soils by differential thermal analysis, before and after heating to 600~ and by infra-red spectroscopy indicates that these contain a proportion of highly hydrated amorphous material, resembling allophane in its properties, and that this component is particularly high in clays from the surface horizons with the greatest organ...

to be quite compatible with the original analytical scheme. Incidentally, El-Attar and Jackson (1973) have observed considerable thermal decomposition at 550~ of Fe-rich layers and/or interlayers in montmorillonitic soils of Nile River alluvium. Additional information that can be deduced from the above procedure is the CEC and K § -fixation capacity of the amorphous constituents of the clays pr...

Clay minerals on Mars have commonly been interpreted as the remnants of pervasive water-rock interaction during the Noachian period (>3.7Ga). This history has been partly inferred by observations of clays in central peaks of impact craters, which often are presumed uplifted from depth. However, combined mineralogical and morphological analyses of individual craters have shown that some central ...

background: the removal of toxic metals from sewage and wastewaters is one of the most important concerns in the twenty first century. the removal of poisonous cr(vi) from aqueous solution by different low-cost available nanoporous adsorbents was investigated in the present study.  methods: fumed silica, bentonite (bn), hydrotalcite (ht), mcm-41, na-y, mordenite (mor) and sapo-34 were used at d...

Due to their excellent properties, clays have been widely used in several applications, particularly in catalysis. In this paper, three clays were used as heterogeneous photo-Fenton catalysts for phenol and tyrosol oxidations. Particular attention was given to the effect of the main operating conditions on the process performance. A total conversion was obtained for both organic pollutants with...

Zeolite-geopolymer hybrid materials have been formed when kaolin was used as a starting material. Their characteristics are of interest because they can have a wide pore size distribution with micro- and meso-pores due to the zeolite and geopolymer, respectively. In this study, Zeolite-geopolymer hybrid bulk materials were fabricated using four kinds of kaolinitic clays (a halloysite and three ...

The void index is a relative quantity measuring the position of the current void ratio of a clay against the void ratios of the clay at two specific vertical effective stresses (i.e., σ v ′ = 100 kPa and σ v ′ =1000 kPa). Based on this concept, a simple systematic tool is proposed for estimating the compression behaviour of reconstituted clays over a wide range of stresses and water contents. F...